The polyol process: a unique method for easy access to metal nanoparticles with tailored sizes, shapes and compositions

F Fiévet, S Ammar-Merah, R Brayner, F Chau… - Chemical Society …, 2018 - pubs.rsc.org
After about three decades of development, the polyol process is now widely recognized and
practised as a unique soft chemical method for the preparation of a large variety of …

Ligand-promoted palladium-catalyzed aerobic oxidation reactions

D Wang, AB Weinstein, PB White, SS Stahl - Chemical reviews, 2017 - ACS Publications
Palladium-catalyzed aerobic oxidation reactions have been the focus of industrial
application and extensive research efforts for nearly 60 years. A significant transition …

Highly practical copper (I)/TEMPO catalyst system for chemoselective aerobic oxidation of primary alcohols

JM Hoover, SS Stahl - Journal of the American Chemical Society, 2011 - ACS Publications
Aerobic oxidation reactions have been the focus of considerable attention, but their use in
mainstream organic chemistry has been constrained by limitations in their synthetic scope …

Mechanism of copper (I)/TEMPO-catalyzed aerobic alcohol oxidation

JM Hoover, BL Ryland, SS Stahl - Journal of the American …, 2013 - ACS Publications
Homogeneous Cu/TEMPO catalyst systems (TEMPO= 2, 2, 6, 6-tetramethylpiperidine-N-
oxyl) have emerged as some of the most versatile and practical catalysts for aerobic alcohol …

Overcoming the “Oxidant Problem”: Strategies to Use O2 as the Oxidant in Organometallic C–H Oxidation Reactions Catalyzed by Pd (and Cu)

AN Campbell, SS Stahl - Accounts of Chemical Research, 2012 - ACS Publications
Oxidation reactions are key transformations in organic chemistry because they can increase
chemical complexity and incorporate heteroatom substituents into carbon-based molecules …

Rhodium (III)-catalyzed arene and alkene C− H bond functionalization leading to indoles and pyrroles

DR Stuart, P Alsabeh, M Kuhn… - Journal of the American …, 2010 - ACS Publications
Recently, the rhodium (III)-complex [Cp* RhCl2] 2 1 has provided exciting opportunities for
the efficient synthesis of aromatic heterocycles based on a rhodium-catalyzed C− H bond …

Role of N-Acyl Amino Acid Ligands in Pd(II)-Catalyzed Remote C–H Activation of Tethered Arenes

GJ Cheng, YF Yang, P Liu, P Chen… - Journal of the …, 2014 - ACS Publications
A combined experimental/computational study on the amino acid ligand-assisted Pd-
catalyzed C–H bond activation reveals a mechanism in which the amino acid acts as both a …

Recent developments in palladium (nano) catalysts supported on polymers for selective and sustainable oxidation processes

M Nasrollahzadeh, M Sajjadi, M Shokouhimehr… - Coordination Chemistry …, 2019 - Elsevier
This review describes the recent advances in the fabrication, characterization and
applications of palladium nanoparticles (Pd NPs)/complexes supported on polymers …

An Efficient Rh/O2 Catalytic System for Oxidative C–H Activation/Annulation: Evidence for Rh(I) to Rh(III) Oxidation by Molecular Oxygen

G Zhang, L Yang, Y Wang, Y Xie… - Journal of the American …, 2013 - ACS Publications
A novel and efficient Rh/O2 catalytic system has been developed and shown to catalyze
highly efficient oxidative C–H activation/annulation reactions, producing a broad range of …

Ligand-modulated palladium-catalyzed aerobic alcohol oxidations

MS Sigman, DR Jensen - Accounts of chemical research, 2006 - ACS Publications
The discovery and investigation of ligand-modulated Pd-catalyzed aerobic alcohol
oxidations is documented. The project has evolved from a simple empirical discovery that (−) …