Rare-earth metal–organic frameworks: from structure to applications

F Saraci, V Quezada-Novoa… - Chemical Society …, 2020 - pubs.rsc.org
In the past 30 years, metal–organic frameworks (MOFs) have garnered widespread attention
owing to their diverse chemical structures, and tunable properties. As a result, MOFs are of …

Magnetic cooling: a molecular perspective

P Konieczny, W Sas, D Czernia, A Pacanowska… - Dalton …, 2022 - pubs.rsc.org
The magnetocaloriceffect is considered as an energy-efficient and environmentally friendly
technique which can take cooling technology to the next level. Apart from its commercial …

An ultrastable luminescent metal–organic framework for selective sensing of nitroaromatic compounds and nitroimidazole-based drug molecules

BX Dong, YM Pan, WL Liu, YL Teng - Crystal Growth & Design, 2018 - ACS Publications
A chemically stable and thermally stable luminescent Cd (II)-based metal–organic
framework (MOF),[Cd3 (DBPT) 2 (H2O) 4]· 5H2O (1), featuring an open Lewis basic triazolyl …

A dual luminescent chemosensor derived from a europium (III) metal-organic framework for quantitative detection of phosphate anions and acetylacetone in aqueous …

L Li, JY Zou, SY You, YW Liu, HM Cui, SW Zhang - Dyes and Pigments, 2020 - Elsevier
A luminescent europium (III) metal-organic framework (MOF){[Eu (bcpt)(HCOO)]· 0.5 H 2 O}
n (1) has been synthesized under solvothermal conditions by adopting a elongated ligand …

Two series of microporous lanthanide–organic frameworks with different secondary building units and exposed Lewis base active sites: sensing, dye adsorption, and …

J Jin, G Yang, Y Liu, S Cheng, J Liu, D Wu… - Inorganic …, 2018 - ACS Publications
Two series of new lanthanide complexes,{[Ln (L) 1.5 (H2O)]· DMA· 4H2O} n (1-Ln, Ln= Tb,
Gd, and Dy) and {[La2 (L) 3]· 4H2O} n (2-La), were prepared successfully by Ln3+ ions and …

Magnetic Slow Relaxation in a Metal–Organic Framework Made of Chains of Ferromagnetically Coupled Single‐Molecule Magnets

G Huang, G Fernandez‐Garcia… - … A European Journal, 2018 - Wiley Online Library
We report the study of a Dy‐based metal–organic framework (MOF) with unprecedented
magnetic properties. The compound is made of nine‐coordinated DyIII magnetic building …

Cu (II) MOFs based on bipyridyls: topology, magnetism, and exploring sensing ability toward multiple nitroaromatic explosives

MN Ahamad, M Shahid, M Ahmad, F Sama - ACS omega, 2019 - ACS Publications
In this work, a series of three copper (II) metal-organic frameworks (MOFs),[Cu (4, 4′-DP)
Cl] n (1),[Cu (4, 4′-DP) 0.5 Cl] n (2), and [Cu (4, 4′-TMDP) Cl] n (3)(4, 4′-DP= 4, 4 …

Blue-Emitting Ligand-Mediated Assembly of Rare-Earth MOFs toward White-Light Emission, Sensing, Magnetic, and Catalytic Studies

K Manna, JP Sutter, S Natarajan - Inorganic Chemistry, 2022 - ACS Publications
New lanthanide carboxylate compounds with two-(2D) and three-dimensional (3D)
structures have been prepared by employing 2, 5-bis (prop-2-yn-1-yloxy) terephthalic acid …

A Tb-MOF anion, porous coordination framework constructed with oxalate ligand: Crystal structure, adsorption properties, and luminescence sensing

R Cui, R Li, Z Li, M Wei, X Wang, X Li - Dyes and Pigments, 2021 - Elsevier
The reaction of Tb (NO) 3· 6H 2 O and potassium oxalate (ox) yielded the coordination
framework,[CH 3 NH 2 CH 3][Tb (ox) 2 (H 2 O)]· 3H 2 O (Tb-MOF). It shows a 3D anionic …

Lanthanide coordination polymers constructed from the asymmetrical N-heterocyclic rigid carboxylate: Synthesis, crystal structures, luminescence properties and …

LN Zheng, FH Wei, HM Hu, C Bai, XL Yang, X Wang… - Polyhedron, 2019 - Elsevier
Three new series of lanthanide coordination polymers [LnL 2 (H 2 O) 4] n· nNO 3 (Ln= Eu
(1), Tb (2), Sm (3), Gd (4), Dy (5), Ho (6), Nd (7)),[LnL 2 (H 2 O) 4] n· nCl (Ln= Yb (8), Er (9) …