N-Heterocyclic carbenes as tunable ligands for catalytic metal surfaces

M Koy, P Bellotti, M Das, F Glorius - Nature Catalysis, 2021 - nature.com
Heterogeneous catalysts represent the backbone of many industrial processes and thus
have a considerable societal impact. The active sites of these heterogeneous catalysts are …

N-Heterocyclic Carbenes in Materials Chemistry

CA Smith, MR Narouz, PA Lummis, I Singh… - Chemical …, 2019 - ACS Publications
N-Heterocyclic carbenes (NHCs) have become one of the most widely studied class of
ligands in molecular chemistry and have found applications in fields as varied as catalysis …

N-heterocyclic carbene coordinated metal nanoparticles and nanoclusters

H Shen, G Tian, Z Xu, L Wang, Q Wu, Y Zhang… - Coordination Chemistry …, 2022 - Elsevier
N-heterocyclic carbenes (NHCs) represent one of the most important organic ligands in
coordination chemistry, and have been recently attracting increasing attention in …

Nano-magnetite (Fe 3 O 4) as a support for recyclable catalysts in the development of sustainable methodologies

MB Gawande, PS Branco, RS Varma - Chemical Society Reviews, 2013 - pubs.rsc.org
Surface functionalization of nano-magnetic nanoparticles is a well-designed way to bridge
the gap between heterogeneous and homogeneous catalysis. The introduction of magnetic …

Carbene ligands in surface chemistry: from stabilization of discrete elemental allotropes to modification of nanoscale and bulk substrates

AV Zhukhovitskiy, MJ MacLeod, JA Johnson - Chemical Reviews, 2015 - ACS Publications
Carbenes are perhaps the most versatile reactive intermediates in chemistry. Since the
original visions of “methylene” by Dumas 1 in 1835 and a generalization of this vision by Nef …

Immobilization of N-heterocyclic carbene compounds: a synthetic perspective

R Zhong, AC Lindhorst, FJ Groche… - Chemical Reviews, 2017 - ACS Publications
Over the course of the past 15 years the success story of N-heterocyclic carbene (NHC)
compounds in organic, inorganic, and organometallic chemistry has been extended to …

N-heterocyclic carbenes capped metal nanoparticles: An overview of their catalytic scope

M Ghosh, S Khan - ACS Catalysis, 2023 - ACS Publications
N-Heterocyclic carbenes (NHCs) have become the most celebrated ligands in various fields
of chemistry due to their unique electronic properties. 1− 5 Since the first stable N …

Robust gold nanorods stabilized by bidentate N-heterocyclic-carbene–thiolate ligands

MJ MacLeod, AJ Goodman, HZ Ye, HVT Nguyen… - Nature Chemistry, 2019 - nature.com
Although N-heterocyclic carbenes (NHCs) have demonstrated outstanding potential for use
as surface anchors, synthetic challenges have limited their application to either large planar …

Supported Au Nanoparticles with N-Heterocyclic Carbene Ligands as Active and Stable Heterogeneous Catalysts for Lactonization

R Ye, AV Zhukhovitskiy, RV Kazantsev… - Journal of the …, 2018 - ACS Publications
Attachment of N-heterocyclic carbenes (NHCs) on the surface of metal nanoparticle (NP)
catalysts permits fine-tuning of catalytic activity and product selectivity. Yet, NHC-coated Au …

Negatively charged N-heterocyclic carbene-stabilized Pd and Au nanoparticles and efficient catalysis in water

A Ferry, K Schaepe, P Tegeder, C Richter… - ACS …, 2015 - ACS Publications
Herein we describe the synthesis of negatively charged N-heterocyclic carbene (NHC)-
functionalized palladium and gold nanoparticles (NPs), which are stable in water for over 3 …