Fluorinated carbenes take an important position in the synthesis of fluorine-containing
molecules in organic synthesis. When carbon centered carbenes are installed with fluorides …

Single C− F transformations of aromatic trifluoromethyl compounds are challenging issues
due to the strong C− F bond. We have recently developed selective methods for single C− F …

An alternative strategy for the mechanochemical defluorinative acylation of ortho‐
hydroxyarylenaminones has been developed to synthesise 3‐acylchromones utilizing CF3 …

Among a wide array of synthetic amides, N-aryl/alkyl amides are an important class of
structural motifs having significant importance in pharmaceutical and agrochemical …

Selective defluorinative functionalization of trifluoromethyl group (–CF3) is an attractive
synthetic route to the pharmaceutically privileged fluorine-containing moiety. Herein, we …

The stoichiometric defluorinative functionalization of ArCF3 is a conceptually appealing
research target. It enables the challenging late-stage functionalization of CF3-containing …

The amide bond is prominent in natural and synthetic organic molecules endowed with
activity in various fields. Among a wide array of amide synthetic methods, substitution on a …

Abstract Five organotin (IV) derivatives (1–5) of general formula R 3 SnL and R 2 SnL 2,
where R= C 4 H 9 {1, and 3}, CH 3 {2 and 4}, C 6 H 5 {5} and L represents 4 …

Since the introduction of the TM‐catalyzed cross‐couplings their scope of starting materials
has been growing systematically, allowing for more flexible design of synthetic routes with …

The traditional Eschweiler–Clarke reaction is a three-component process involving
formaldehyde, amine, and formic acid. In this work, we showed that the reductive potential of …