Molecular Engineering of Metal Alkoxides for Solution Phase Synthesis of High‐Tech Metal Oxide Nanomaterials

S Mishra, S Daniele - Chemistry–A European Journal, 2020 - Wiley Online Library
The 'bottom‐up'synthesis of inorganic nanomaterials with precision at the atomic/molecular
level offers many opportunities for the design and improvement of the nanomaterials for …

A “Molecular Water Pipe”: A Giant Tubular Cluster {Dy72} Exhibits Fast Proton Transport and Slow Magnetic Relaxation

L Qin, YZ Yu, PQ Liao, W Xue, Z Zheng… - Advanced …, 2016 - Wiley Online Library
The studies of water-mediated proton-conducting materials have recently been extended to
porous crystalline solids, such as metal–organic frameworks (MOFs) or porous coordination …

High spin cycles: topping the spin record for a single molecule verging on quantum criticality

A Baniodeh, N Magnani, Y Lan, G Buth… - npj Quantum …, 2018 - nature.com
The cyclisation of a short chain into a ring provides fascinating scenarios in terms of
transforming a finite array of spins into a quasi-infinite structure. If frustration is present …

From the {FeIII2Ln2} Butterfly's Perspective: the Magnetic Benefits and Challenges of Cooperativity within 3 d–4 f Based Coordination Clusters

Y Peng, H Kaemmerer… - Chemistry–A European …, 2021 - Wiley Online Library
In this Review we discuss the tuning handles which can be used to steer the magnetic
properties of FeIII‐4 f “butterfly” compounds. The majority of presented compounds were …

Synthesis, characterization, spectral studies and evaluation of noncovalent interactions in co-crystal of μ-oxobridged polymeric copper (II) complex derived from …

S Parvarinezhad, M Salehi, M Kubicki - Journal of Molecular Structure, 2022 - Elsevier
The new co-crystal of μ-oxobridged polymeric copper (II) complex {[0.714 (9) Cu II 2 (HL-CH
2 OH) 2].[0.286 (9) Cu II 2 (HL-CHO 2 H) 2]} n with Schiff base ligand derived from …

Au20(tBu3P)8: A Highly Symmetric Metalloid Gold Cluster in Oxidation State 0

F Fetzer, N Pollard, NC Michenfelder… - Angewandte Chemie …, 2022 - Wiley Online Library
Metalloid gold clusters have unique properties with respect to size and structure and are key
intermediates in studying transitions between molecular compounds and the bulk phase of …

Large Hexadecametallic {MnIII–LnIII} Wheels: Synthesis, Structural, Magnetic, and Theoretical Characterization

KR Vignesh, SK Langley, B Moubaraki… - … A European Journal, 2015 - Wiley Online Library
The synthesis, gas sorption studies, magnetic properties, and theoretical studies of new
molecular wheels of core type {MnIII8LnIII8}(Ln= Dy, Ho, Er, Y and Yb), using the ligand …

Single-molecule toroic design through magnetic exchange coupling

HL Zhang, YQ Zhai, L Qin, L Ungur, H Nojiri, YZ Zheng - Matter, 2020 - cell.com
Toroidal molecular magnets represent promising candidates for next-generation ultra-dense
information storage. These wheel-like molecules are able to store one bit per molecule …

Nanoscale magnetic arrays through block copolymer templating of polyoxometalates

DRM Clyde, DL Cortie, S Granville, DC Ware… - Nano Letters, 2024 - ACS Publications
Magnetic nanoarrays promise to enable new energy-efficient computations based on
spintronics or magnonics. In this work, we present a block copolymer-assisted strategy for …

Cocrystallization of Chiral 3d-4f Clusters {Mn10Ln6} and {Mn6Ln2}

X Wang, MH Du, H Xu, LS Long, XJ Kong… - Inorganic …, 2021 - ACS Publications
Cocrystallization of different metal nanoclusters facilitates the preparation of cluster-based
nanomaterials with enhanced properties. Herein, two pairs of enantiomeric 3d-4f …