The greener side of polymers in the light of d-block metal complexes as precatalysts

M Pawlak, J Drzeżdżon, D Jacewicz - Coordination Chemistry Reviews, 2023 - Elsevier
Polyolefins are the most widely used and needed polymers in the world. Their
polymerization process is a topic of great interest among scientists. Not only do polyolefins …

Coordination of ε-Caprolactone to a Cationic Niobium (V) Alkoxide Complex: Fundamental Insight into Ring-Opening Polymerization via Coordination–Insertion

A Buchard, MG Davidson, G Gobius du Sart… - Inorganic …, 2023 - ACS Publications
We report three niobium-based initiators for the catalytic ring-opening polymerization (ROP)
of ε-caprolactone, exhibiting good activity and molecular weight control. In particular, we …

Ethylene polymerization with thermally robust vanadium (III) tris (2-pyridyl) borate complexes

J Qian, RJ Comito - Organometallics, 2023 - ACS Publications
Despite the useful selectivity offered by vanadium catalysts for olefin polymerization, their
implementation under practical conditions remains limited by poor productivity and thermal …

A robust vanadium (v) tris (2-pyridyl) borate catalyst for long-lived high-temperature ethylene polymerization

J Qian, RJ Comito - Organometallics, 2021 - ACS Publications
Soluble vanadium catalysts are highly coveted for their selectivity in olefin polymerization.
However, their utility is limited by rapid deactivation, especially at scalable temperatures …

Dinuclear oxidovanadium complexes with dihydrazone ligands derived from diethyl 2, 6-dimethylpyridine-3, 5-dicarboxylate obtained from Hantzsch reaction; crystal …

F Soltani, R Bikas, N Heydari… - New Journal of …, 2023 - pubs.rsc.org
Two new dihydrazone ligands (H4L1 and H4L2) have been prepared from Hantzsch
pyridine ester and after characterization by analytical methods, they have been used in the …

Vanadium complexes as potential metal-based antimicrobial drugs

M Kumari, M Thakur, S Sharma, M Sharma… - JBIC Journal of …, 2024 - Springer
Radical increase of antibiotic resistance among microbes has become a serious problem for
clinics all over the world that has led to the need for search of novel types of antimicrobial …

Vanadium Complexes Derived from O,N,O-tridentate 6-bis(o-hydroxyalkyl/aryl)pyridines: Structural Studies and Use in the Ring-Opening Polymerization of ε …

MRJ Elsegood, W Clegg, C Redshaw - Catalysts, 2023 - mdpi.com
Interaction of [VO (O i Pr) 3] with 6-bis (o-hydroxyaryl) pyridine, 2, 6-{HOC (Ph) 2CH2} 2
(NC5H3), LH2, afforded [VO (O i Pr) L](1) in good yield. The reaction of LNa2, generated in …

Poly (Biphenol/biphenoquinone-Vanadium (IV)) modified electrode as selective sensor for detection of 4-nitrophenol

S Narouie, GH Rounaghi, H Saravani… - Microchemical …, 2022 - Elsevier
In the present work, we report a new method for facile and effective synthesis of poly
(biphenol/biphenoquinone-vanadium (IV))(poly BP/BQ-V IV) for the first time. The poly …

Achieving ultra‐high molecular weight polyethylenes by vanadium aroylhydrazine‐arylolates

H Suo, AM Faisca Phillips, M Satrudhar… - Journal of Polymer …, 2023 - Wiley Online Library
A series of vanadium (V) aroylhydrazine‐arylolates is employed in ethylene polymerization
to produce ultra‐high molecular weight polyethylene (UHMWPE), surprisingly extending to …

Synthesis, characterization and ethylene (Co) polymerization of binuclear Vanadium (IV) catalysts based on xanthene-bridged bis-salicylaldiminato ligands

S Ren, X Xiao, P Huang, M Zhou, T Li, Q You… - European Polymer …, 2024 - Elsevier
Bimetallic complexes have attracted much attention due to their excellent catalytic
performances in many fields. Herein six xanthene-bridged bis-salicylaldiminato [ON] …