The possibility that the intramolecular Tr⋯ S triel bond is strengthened by resonance is
examined by quantum chemical calculations within the planar five-membered ring of TrH2 …

Malondialdehyde (MDA) engages in a triel bond (TrB) with TrX3 (Tr= B and Al; X= H, F, Cl,
and Br) in three modes, in which the hydroxyl O, carbonyl O, and central carbon atoms of …

The internal dynamics of a 2-chloromalonaldehyde (2-ClMA) molecule, possessing a strong
internal hydrogen bond (IHB), was examined by means of matrix isolation spectroscopy in a …

Molecules of the β-diketone and β-dialdehyde families were trapped in solid parahydrogen
(pH2) to investigate the vibrational behavior of systems containing an intramolecular …

Parahydrogen (p H2) quantum solids are excellent matrix isolation hosts for studying the
rovibrational dynamics and nuclear spin conversion (NSC) kinetics of molecules containing …

Isomerization of 2-chloromalonaldehyde (2-ClMA) is explored giving access to new
experimental data on this derivative of malonaldehyde, not yet studied much. Experiments …

A molecular dynamics deposition model has been used to simulate the growth of rare gas
matrices doped with atoms of the group 12 elements zinc, cadmium and mercury. This study …

A deposition model to simulate the growth of doped rare gas crystals is used. The study
involves organic molecules with a single intramolecular hydrogen bond such as …

The structure of trifluoroacetylacetone in argon and nitrogen matrices and association with
water molecules were studied by the means of Fourier transform infrared absorption …

Electronic phosphorescence and infrared absorption spectra of methylcyanodiacetylene
(CH 3 C 5 N) are revisited using matrix isolation in solid parahydrogen and neon. Band …