The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …

Photocatalytic generation of phosphoranyl radicals is fast emerging as an essential method
for the generation of diverse and valuable radicals, typically via deoxygenation or …

Cyclopropanes are an important class of building blocks in organic synthesis. Herein, a ring‐
opening/arylcarboxylation/acylation cascade reaction for the 1, 3‐difunctionalization of aryl …

Light-powered catalysis has found broad utility as a chemical transformation strategy, with
widespread impact on energy, environment, drug discovery and human health. A noteworthy …

A photoredox-catalyzed divergent 1, 2-dicarbonylation and hydroacylation of alkenes with
acid anhydride is presented. This approach offers a mild and efficient entry to 1, 4-dicarbonyl …

Exploiting β-scission in aminophosphoranyl radicals for radical-mediated transformations
has been a longstanding challenge. In this study, we investigated the untapped potential of …

An unprecedented photoredox‐catalyzed phosphine‐mediated deoxygenation of
hexafluoroacetone hydrate was established to accomplish the hydroxylpolyfluoroalkylation …

A nickel-catalyzed decarbonylative thioetherification of carboxylic acids with thiols was
developed. Under the reaction conditions, benzoic acids, cinnamic acids, and benzyl …

An intermolecular 1, 2-diacylation of alkenes is disclosed via cooperative N-heterocyclic
carbene and photoredox catalysis under the mediation of PPh3 and Cs2CO3. This protocol …

The construction of C–S bonds is an important process in synthetic, medicinal and materials
chemistry. Thiols are usually employed as the starting materials to provide the S source …