Metal sites in zeolites: synthesis, characterization, and catalysis

Q Zhang, S Gao, J Yu - Chemical reviews, 2022 - ACS Publications
Zeolites with ordered microporous systems, distinct framework topologies, good spatial
nanoconfinement effects, and superior (hydro) thermal stability are an ideal scaffold for …

Surface and interface coordination chemistry learned from model heterogeneous metal nanocatalysts: from atomically dispersed catalysts to atomically precise …

W Jing, H Shen, R Qin, Q Wu, K Liu, N Zheng - Chemical Reviews, 2022 - ACS Publications
The surface and interface coordination structures of heterogeneous metal catalysts are
crucial to their catalytic performance. However, the complicated surface and interface …

Single‐Atom Fe Catalysts for Fenton‐Like Reactions: Roles of Different N Species

Y Xiong, H Li, C Liu, L Zheng, C Liu… - Advanced …, 2022 - Wiley Online Library
Recognizing and controlling the structure–activity relationships of single‐atom catalysts
(SACs) is vital for manipulating their catalytic properties for various practical applications …

Metal–support interactions in metal/oxide catalysts and oxide–metal interactions in oxide/metal inverse catalysts

Y Li, Y Zhang, K Qian, W Huang - ACS Catalysis, 2022 - ACS Publications
Solid catalysts usually consist of multicomponents, within which interfacial interactions have
been recognized as a key factor affecting structures and catalytic performance. Metal …

Engineering heterogeneous catalysis with strong metal–support interactions: characterization, theory and manipulation

T Pu, W Zhang, M Zhu - Angewandte Chemie International …, 2023 - Wiley Online Library
Strong metal–support interactions (SMSI) represent a classic yet fast‐growing area in
catalysis research. The SMSI phenomenon results in the encapsulation and stabilization of …

Dynamic interplay between metal nanoparticles and oxide support under redox conditions

H Frey, A Beck, X Huang, JA van Bokhoven… - Science, 2022 - science.org
The dynamic interactions between noble metal particles and reducible metal-oxide supports
can depend on redox reactions with ambient gases. Transmission electron microscopy …

Interfacial compatibility critically controls Ru/TiO2 metal-support interaction modes in CO2 hydrogenation

J Zhou, Z Gao, G Xiang, T Zhai, Z Liu, W Zhao… - Nature …, 2022 - nature.com
Supports can widely affect or even dominate the catalytic activity, selectivity, and stability of
metal nanoparticles through various metal-support interactions (MSIs). However, underlying …

Surface coordination chemistry of atomically dispersed metal catalysts

R Qin, K Liu, Q Wu, N Zheng - Chemical Reviews, 2020 - ACS Publications
Atomically dispersed metal catalysts (ADCs), as an emerging class of heterogeneous
catalysts, have been widely investigated during the past two decades. The atomic dispersion …

Restructuring of titanium oxide overlayers over nickel nanoparticles during catalysis

M Monai, K Jenkinson, AEM Melcherts, JN Louwen… - Science, 2023 - science.org
Reducible supports can affect the performance of metal catalysts by the formation of
suboxide overlayers upon reduction, a process referred to as the strong metal–support …

Nanoscale engineering of catalytic materials for sustainable technologies

S Mitchell, R Qin, N Zheng, J Pérez-Ramírez - Nature nanotechnology, 2021 - nature.com
Nanostructured materials of diverse architecture are ubiquitous in industrial catalysis. They
offer exciting prospects to tackle various sustainability challenges faced by society. Since the …