MOF-based membranes for gas separations

Q Qian, PA Asinger, MJ Lee, G Han… - Chemical …, 2020 - ACS Publications
Metal–organic frameworks (MOFs) represent the largest known class of porous crystalline
materials ever synthesized. Their narrow pore windows and nearly unlimited structural and …

Removal of carbon dioxide using zeolitic imidazolate frameworks: adsorption and conversion via catalysis

HN Abdelhamid - Applied Organometallic Chemistry, 2022 - Wiley Online Library
Carbon dioxide (CO2) is one of the culprit causes of global climatic changes. Furthermore,
the efficient separation of CO2 from other gaseous mixtures using zeolitic imidazolate …

MOFs in the time domain

DJ Cerasale, DC Ward, TL Easun - Nature Reviews Chemistry, 2022 - nature.com
Many of the proposed applications of metal–organic framework (MOF) materials may fail to
materialize if the community does not fully address the difficult fundamental work needed to …

Solid-state NMR spectroscopy: an advancing tool to analyse the structure and properties of metal–organic frameworks

E Brunner, M Rauche - Chemical Science, 2020 - pubs.rsc.org
Metal–organic frameworks (MOFs) gain increasing interest due to their outstanding
properties like extremely high porosity, structural variability, and various possibilities for …

Combining In Situ Techniques (XRD, IR, and 13C NMR) and Gas Adsorption Measurements Reveals CO2-Induced Structural Transitions and High CO2/CH4 …

K Roztocki, M Rauche, V Bon, S Kaskel… - … Applied Materials & …, 2021 - ACS Publications
Flexible metal–organic frameworks (MOFs) are promising materials in gas-related
technologies. Adjusting the material to processes requires understanding of the flexibility …

Probing molecular motions in metal-organic frameworks with solid-state NMR

Y Fu, H Guan, J Yin, X Kong - Coordination Chemistry Reviews, 2021 - Elsevier
Molecular motions in metal-organic frameworks (MOFs) are important phenomena that
involve the sorption of gases, the rotation of linkers, the diffusion of ions, the reaction of …

Solid‐State NMR Spectroscopy: A Powerful Technique to Directly Study Small Gas Molecules Adsorbed in Metal–Organic Frameworks

YTA Wong, V Martins, BEG Lucier… - Chemistry–A European …, 2019 - Wiley Online Library
Metal–organic frameworks (MOFs) have shown great potential in gas separation and
storage, and the design of MOFs for these purposes is an on‐going field of research. Solid …

In Situ 13C NMR Spectroscopy Study of CO2/CH4 Mixture Adsorption by Metal–Organic Frameworks: Does Flexibility Influence Selectivity?

M Sin, N Kavoosi, M Rauche, J Pallmann, S Paasch… - Langmuir, 2019 - ACS Publications
Metal–organic frameworks are promising candidates for selective separation processes
such as CO2 removal from methane (natural gas sweetening). Framework flexibility, that is …

Unexpected Diffusion Anisotropy of Carbon Dioxide in the Metal–Organic Framework Zn2(dobpdc)

AC Forse, MI Gonzalez, RL Siegelman… - Journal of the …, 2018 - ACS Publications
Metal–organic frameworks are promising materials for energy-efficient gas separations, but
little is known about the diffusion of adsorbates in materials featuring one-dimensional …

Sorption and transport of vapors in ZIF-11: adsorption, diffusion, and linker flexibility

BR Pimentel, ML Jue, EK Zhou… - The Journal of …, 2019 - ACS Publications
The adsorption and diffusion of alcohol and hydrocarbon vapors in zeolitic imidazolate
frameworks (ZIF)-11 are reported as a function of loading at 308 K. The hydrophobicity of the …