Beyond the average: spatial and temporal fluctuations in oxide glass-forming systems

KA Kirchner, DR Cassar, ED Zanotto, M Ono… - Chemical …, 2022 - ACS Publications
Atomic structure dictates the performance of all materials systems; the characteristic of
disordered materials is the significance of spatial and temporal fluctuations on composition …

[PDF][PDF] Discovery of the intermediate phase in chalcogenide glasses

P Boolchand, DG Georgiev, B Goodman - Journal of Optoelectronics …, 2001 - apps.dtic.mil
The microscopic origin of glass formation has been debated for over 50 years. It is generally
believed that glass formation is a kinetic phenomenon [1], although the aspects of liquid …

The structure of amorphous, crystalline and liquid GeO2

M Micoulaut, L Cormier… - Journal of Physics …, 2006 - iopscience.iop.org
Germanium dioxide (GeO 2) is a chemical analogue of SiO 2. Furthermore, it is also to some
extent a structural analogue, as the low-and high-pressure short-range order (tetrahedral …

Rigidity transitions and molecular structure of glasses

DG Georgiev, P Boolchand, M Micoulaut - Physical Review B, 2000 - APS
T-modulated differential scanning calorimetry measurements on bulk As x Se 1− x glasses
show that the glass transition temperature T g (x) variation at x< 0.12 is linear with a slope dT …

Relaxation and physical aging in network glasses: a review

M Micoulaut - Reports on Progress in Physics, 2016 - iopscience.iop.org
Recent progress in the description of glassy relaxation and aging are reviewed for the wide
class of network-forming materials such as GeO 2, Ge x Se 1− x, silicates (SiO 2–Na 2 O) or …

Pressure Raman effects and internal stress in network glasses

F Wang, S Mamedov, P Boolchand, B Goodman… - Physical Review B …, 2005 - APS
Raman scattering from binary Ge x Se 1− x glasses under hydrostatic pressure shows onset
of a steady increase in the frequency of modes of corner-sharing Ge Se 4 tetrahedral units …

Atomic scale foundation of temperature-dependent bonding constraints in network glasses and liquids

M Bauchy, M Micoulaut - Journal of Non-Crystalline Solids, 2011 - Elsevier
The behaviour of bonding constraints with temperature is analyzed from an atomic scale
approach (Molecular Dynamics, MD) combined with partial bond angle distributions (PBAD) …

Self-organization and the physics of glassy networks

P Boolchand, G Lucovsky, JC Phillips… - Philosophical …, 2005 - Taylor & Francis
Network glasses are the physical prototype for many self-organized systems, ranging from
proteins to computer science. Conventional theories of gases, liquids and crystals do not …

[PDF][PDF] The structure of silicate melts: a glass perspective

GS Henderson - The Canadian Mineralogist, 2005 - researchgate.net
Glasses are widely used as analogues for the study of silicate melts. Although they are solid
materials, their structure is inherently complex and difficult to study. However, progress has …

Energy landscape and rigidity

GG Naumis - Physical Review E—Statistical, Nonlinear, and Soft …, 2005 - APS
The effects of floppy modes in the thermodynamical properties of a system are studied. From
thermodynamical arguments, we deduce that floppy modes are not at zero frequency and …