Fundamentals of H2 Binding and Reactivity on Transition Metals Underlying Hydrogenase Function and H2 Production and Storage

GJ Kubas - Chemical reviews, 2007 - ACS Publications
Formation of stable iron hydrides on more nucleophilic (electron-rich) metal centers than
those found in hydrogenases with CO ligands would inhibit or at least slow down function …

Materials for hydrogen storage: current research trends and perspectives

AWC van den Berg, CO Areán - Chemical Communications, 2008 - pubs.rsc.org
Storage and transport of hydrogen constitutes a key enabling technology for the advent of a
hydrogen-based energy transition. Main research trends on hydrogen storage materials …

Zeolite-like Metal−Organic Frameworks (ZMOFs) as Hydrogen Storage Platform: Lithium and Magnesium Ion-Exchange and H2-(rho-ZMOF) Interaction Studies

F Nouar, J Eckert, JF Eubank, P Forster… - Journal of the …, 2009 - ACS Publications
Zeolite-like metal− organic frameworks (ZMOFs) are anionic, have readily exchangeable
extra-framework cations, and can be constructed with a variety of organic linkers. ZMOFs …

Surface Interactions and Quantum Kinetic Molecular Sieving for H2 and D2 Adsorption on a Mixed Metal−Organic Framework Material

B Chen, X Zhao, A Putkham, K Hong… - Journal of the …, 2008 - ACS Publications
A rational strategy has been used to immobilize open metal sites in ultramicroporosity for
stronger binding of multiple H2 molecules per unsaturated metal site for H2 storage …

Adsorption and desorption of hydrogen on metal–organic framework materials for storage applications: comparison with other nanoporous materials

KM Thomas - Dalton transactions, 2009 - pubs.rsc.org
Hydrogen adsorption on porous materials is one of the possible methods proposed for
hydrogen storage for transport applications. High pressure experimental studies of a wide …

Interaction of hydrogen with accessible metal sites in the metal–organic frameworks M 2 (dhtp)(CPO-27-M; M= Ni, Co, Mg)

PDC Dietzel, PA Georgiev, J Eckert, R Blom… - Chemical …, 2010 - pubs.rsc.org
Hydrogen molecules adsorbed in the nickel, cobalt, and magnesium analogs of the CPO-27
metal–organic framework at low loadings interact significantly more strongly than those …

Activation of dihydrogen and coordination of molecular H2 on transition metals

GJ Kubas - Journal of Organometallic Chemistry, 2014 - Elsevier
Fifty years ago, when this journal was founded, organometallic chemists could not have
imagined that common small molecules such as dinitrogen and especially dihydrogen could …

Photoactivation of a nanoporous crystal for on-demand guest trapping and conversion

H Sato, R Matsuda, K Sugimoto, M Takata… - Nature materials, 2010 - nature.com
Porous compounds are ubiquitous and indispensable in daily life as adsorbents and
catalysts. The discovery of a new porous compound with unique properties based on …

Exploiting the Kubas interaction in the design of hydrogen storage materials

TKA Hoang, DM Antonelli - Advanced Materials, 2009 - Wiley Online Library
Hydrogen adsorption and storage using solid‐state materials is an area of much current
research interest, and one of the major stumbling blocks in realizing the hydrogen economy …

Hydrogen activation on organometallic complexes and H2 production, utilization, and storage for future energy

GJ Kubas - Journal of Organometallic Chemistry, 2009 - Elsevier
This perspective article serves to highlight the contributions to this special volume of Journal
of Organometallic Chemistry entitled “Organometallics for Energy Conversion”. The key …