Highly stable neutral corrole radical: amphoteric aromatic–antiaromatic switching and efficient photothermal conversion

H Gao, F Wu, Y Zhao, X Zhi, Y Sun… - Journal of the American …, 2022 - ACS Publications
The preparation of novel stable radical systems that survive and may be manipulated under
harsh conditions is essential for their practical applications, such as energy storage and …

Dynamically switchable porphyrin-based molecular tweezer for on− off fullerene recognition

Z Sun, XH Guo, Y Zhao, QY Meng, LJ Xing… - Chinese Chemical …, 2024 - Elsevier
Herein, a novel molecular tweezer based on 2, 2′-bipyridine-bridged porphyrin subunits
was constructed for efficient fullerenes recognition. The syn conformation of the molecule …

Altering the Site of Electron Abstraction in Cobalt Corroles via meso-Trifluoromethyl Substituents

WR Osterloh, N Desbois, P Fleurat-Lessard… - Inorganic …, 2023 - ACS Publications
A mono-DMSO cobalt meso-CF3 corrole, formulated as (CF3) 3CorCo (DMSO), where (CF3)
3Cor is the trianion of 5, 10, 15-tris (trifluoromethyl) corrole, was synthesized and …

Robust free-base and metalated corrole radicals with reduction-induced emission

P Li, C Qu, F Wu, H Gao, C Zhao, Y Zhao… - Chinese Chemical …, 2025 - Elsevier
Preparing free-base porphyrinoid radicals that can function as coordination ligands is a
challenging task. Here we report the synthesis of a stable, free-base benzocorrole (BC) …

Deciphering electronic and structural effects in Copper Corrole/Graphene Hybrids

K Wrighton‐Araneda… - … A European Journal, 2023 - Wiley Online Library
Non‐covalent hybrid materials based on graphene and A3‐type copper corrole complexes
were computationally investigated. The corroles complexes contain strong electron …

One Carbon Ring Expansion of Bipyrrole to Bipyridine Enables Access to a π‐Extended, Non‐innocent, Corrole‐like Ligand

S Samala, JH Lee, Y Park, SJ Hong… - … A European Journal, 2023 - Wiley Online Library
A π‐extended, diaza‐triphenylene embedded, mono‐anionic corrole analogue and its NiII
complex were synthesized from a diaza‐triphenylene precursor, which was obtained from a …

Serendipitous formation of meso-free corroles in the [3+1] porphyrin and [3+2] sapphyrin syntheses

H Uno, S Konishi, J Nakamura, S Mori… - Journal of Porphyrins …, 2023 - World Scientific
During the preparative investigation of π-expanded porphyrinoids based on the retro-Diels-
Alder reaction of bicyclo [2.2. 2] octadiene (BCOD)-fused precursors for benzo-and benzo [k] …

Augmented Magnetic Response and Spin-Transfer in Copper Corrole/Graphene Hybrids-A DFT Study

The search for hybrid materials with outstanding electronic performance is highly
demanding Since copper corroles have emerged as versatile building blocks providing …

[引用][C] Recent developments in corrole radicals

H Gao, F Wu, K Wang, Z Shen - Journal of Porphyrins and …, 2023 - World Scientific
Corrole is a tetrapyrrolic ring-contracted porphyrin analog with one direct pyrrole-pyrrole
link. The corrole macrocycle is electron-rich and easily stabilized in its one electron oxidized …

[引用][C] Spin switching in corrole radical complex

C Yu, H Xiao, H Lu, Y Xie - Chinese Chemical Letters, 2023 - Elsevier