Benzoxazole-terminated liquid crystals with high birefringence and large dielectric anisotropy

K Hu, Q Weng, R Chen, J Li, D Shi, P Chen, A Gao… - Liquid …, 2020 - Taylor & Francis
Six benzoxazole-terminated mesogenic compounds with fluoro substituent at different
positions were prepared and their properties investigated. The compounds give a high …

Improved nematic mesophase stability of benzoxazole-liquid crystals via modification of inter-ring twist angle of biphenyl unit

D Shi, K Hu, P Chen, W Du, A Gao, R Chen… - Liquid …, 2016 - Taylor & Francis
ABSTRACT A series of nematic heterocyclic liquid crystals, 2-(2ʹ-fluoro-4ʹ-alkoxy-1, 1ʹ-
biphenyl-4-yl)-benzoxazole derivatives (coded as nPF (2) PBx) bearing hydrogen (nPF (2) …

Synthesis and properties of allyloxy-based tolane liquid crystals with high negative dielectric anisotropy

R Chen, L Zhao, Z An, X Chen, P Chen - Liquid Crystals, 2017 - Taylor & Francis
ABSTRACT A series of tolane liquid crystals (LCs) containing 2, 3-difluorophenyl and
allyloxy terminal groups have been synthesised via multi-step reactions. Their thermotropic …

Effect of orientation of lateral fluorine atom on the mesophase behaviour of azo/ester molecules with terminal naphthyl group

AA Sultan, AA Fahmi, GR Saad, MM Naoum - Liquid Crystals, 2019 - Taylor & Francis
Two homologous series of the three-ring 4ʹ-(4"-alkoxy-2"-(or 3") fluoro phenylazo)
benzoates terminated with 2-(or 1-) naphthyl groups (I n d&e or II n d&e), respectively, were …

Nematic mesophase enhanced via lateral monofluorine substitution on benzoxazole-liquid crystals

D Shi, K Hu, P Chen, A Gao, W Du, R Chen… - Liquid …, 2016 - Taylor & Francis
Fluorine is widely used as a lateral substituent to modify the physical properties of liquid
crystals. Here, laterally monofluorinated compounds, 2-(4ʹ-alkoxy-2-fluorobiphenyl-4-yl) …

Effect of lateral bromo substituent on the phase behavior of four-ring azo/ester/azo liquid crystalline materials

NHS Ahmed, GR Saad, MM Naoum - Liquid Crystals, 2019 - Taylor & Francis
In order to study the influence of lateral Br substitution on mesophase behaviour, five
homologous series of 4-substituted phenylazo phenyl 4ʹ-(3ʺ-bromo-4ʺ-alkoxyphenylazo) …

Fluorination improves the mesomorphic and photovoltaic performance of rod-like liquid crystal molecules

R Chen, L Wang, Z An, X Chen, P Chen - Dyes and Pigments, 2023 - Elsevier
Molecular modification engineering is an important pathway to develop novel multifunctional
materials. In this work, we designed and synthesized compounds nN-1, nSN, nFN and nFSN …

Synthesis and mesomorphic properties of the nematic mesophase benzoxazole derivatives with big twist angle of difluoro-biphenyl unit

Q Weng, L Duan, P Chen, A Gao, X Chen, Z An - Liquid Crystals, 2019 - Taylor & Francis
Modifying the position and numbers of lateral fluorine substituent is a common method to
design and adjust the mesophase of liquid crystal compounds. Here, a series of 2-(2, 2ʹ …

Preparation and properties of novel liquid crystal ionomers bearing benzoxazole-based mesogenic side-chains and their membranes

M Zhang, G Liu, S Du, R Chen, P Chen, Q Weng… - Journal of Molecular …, 2024 - Elsevier
A new heterocyclic mesogenic compound, 6-[4-(5-chloro-2-benzoxazolyl) phenoxy]-
hexanethiol (CBPHT), is designed and synthesized, which shows an enantiotropic SmC …

Synthesis and mesomorphic properties of benzoxazole derivatives with lateral multifluoro substituents

Q Weng, L Duan, P Chen, D Shi, A Gao, X Chen… - Liquid …, 2019 - Taylor & Francis
Fluorinated aromatics is generally chosen as mesogenic cores to design novel liquid crystal
compounds. Here, a series of benzoxazole derivatives with laterally multifluorinated …