Understanding ligand-protected noble metal nanoclusters at work

MF Matus, H Häkkinen - Nature Reviews Materials, 2023 - nature.com
Ligand-protected noble metal nanoclusters, commonly termed 'monolayer-protected metal
clusters'(MPCs), comprise a common set of structures with an inorganic core stabilized by an …

Single-atom (iron-based) catalysts: synthesis and applications

B Singh, MB Gawande, AD Kute, RS Varma… - Chemical …, 2021 - ACS Publications
Supported single-metal atom catalysts (SACs) are constituted of isolated active metal
centers, which are heterogenized on inert supports such as graphene, porous carbon, and …

Toward active-site tailoring in heterogeneous catalysis by atomically precise metal nanoclusters with crystallographic structures

R Jin, G Li, S Sharma, Y Li, X Du - Chemical Reviews, 2020 - ACS Publications
Heterogeneous catalysis involves solid-state catalysts, among which metal nanoparticles
occupy an important position. Unfortunately, no two nanoparticles from conventional …

Strategic modulation of target-specific isolated Fe, Co single-atom active sites for oxygen electrocatalysis impacting high power Zn–air battery

S Sarkar, A Biswas, EE Siddharthan, R Thapa… - ACS nano, 2022 - ACS Publications
An effective modulation of the active sites in a bifunctional electrocatalyst is essentially
desired, and it is a challenge to outperform the state-of-the-art catalysts toward oxygen …

Supported metal clusters: fabrication and application in heterogeneous catalysis

C Dong, Y Li, D Cheng, M Zhang, J Liu, YG Wang… - ACS …, 2020 - ACS Publications
Different from isolated metal atoms and large metal nanoparticles (NPs), supported metal
clusters (SMCs) possess distinct geometric and electronic structures and thus exhibit …

The effect of coordination environment on the activity and selectivity of single-atom catalysts

Y Zhang, J Yang, R Ge, J Zhang, JM Cairney… - Coordination Chemistry …, 2022 - Elsevier
Traditional heterogeneous catalysts with noble metals as active sites only have surface-
active substances involved in the catalytic reactions, which greatly reduces the material …

Atomically precise noble metal nanoclusters as efficient catalysts: a bridge between structure and properties

Y Du, H Sheng, D Astruc, M Zhu - Chemical reviews, 2019 - ACS Publications
Improving the knowledge of the relationship between structure and properties is
fundamental in catalysis. Recently, researchers have developed a variety of well-controlled …

Single-atom catalysts: synthetic strategies and electrochemical applications

Y Chen, S Ji, C Chen, Q Peng, D Wang, Y Li - Joule, 2018 - cell.com
The performance and the cost of electrocatalysts play the two most vital roles in the
development and application of energy conversion technologies. Single-atom catalysts …

From metal–organic frameworks to single/dual-atom and cluster metal catalysts for energy applications

CC Hou, HF Wang, C Li, Q Xu - Energy & Environmental Science, 2020 - pubs.rsc.org
Single/dual-atom and cluster metal catalysts, with much higher atom-utilization efficiency,
remarkable performance, good recyclability and unique properties, have emerged as a new …

Atomically precise clusters of noble metals: emerging link between atoms and nanoparticles

I Chakraborty, T Pradeep - Chemical reviews, 2017 - ACS Publications
Atomically precise pieces of matter of nanometer dimensions composed of noble metals are
new categories of materials with many unusual properties. Over 100 molecules of this kind …