Cluster-based single-molecule magnets
CJ Milios, REP Winpenny - Molecular Nanomagnets and Related …, 2015 - Springer
This review covers single-molecule magnets, not only focussing on developments since
2005 but also including coverage of earlier work where necessary for understanding of …
2005 but also including coverage of earlier work where necessary for understanding of …
Coordination clusters of 3d-metals that behave as single-molecule magnets (SMMs): synthetic routes and strategies
D Maniaki, E Pilichos, SP Perlepes - Frontiers in Chemistry, 2018 - frontiersin.org
The area of 3d-metal coordination clusters that behave as Single-Molecule Magnets (SMMs)
is now quite mature within the interdisciplinary field of Molecular Magnetism. This area has …
is now quite mature within the interdisciplinary field of Molecular Magnetism. This area has …
A Family of 3D Coordination Polymers Composed of Mn19 Magnetic Units
EE Moushi, TC Stamatatos… - Angewandte Chemie …, 2006 - Wiley Online Library
The crystal structure of {1· 3 H2O} 1, in the cubic space group P213,[6] reveals that 1 (Figure
1a) is a mixed-valent complex, containing seven MnII ions and twelve MnIII ions, as …
1a) is a mixed-valent complex, containing seven MnII ions and twelve MnIII ions, as …
Diol-type ligands as central 'players' in the chemistry of high-spin molecules and single-molecule magnets
AJ Tasiopoulos, SP Perlepes - Dalton Transactions, 2008 - pubs.rsc.org
The combination of diol-type ligands with paramagnetic transition metal ions has led to the
isolation of a host of new homometallic and heterometallic clusters, high-spin molecules and …
isolation of a host of new homometallic and heterometallic clusters, high-spin molecules and …
Synthetic Factors Determining the Curvature and Nuclearity of the Giant Mn70 and Mn84 Clusters with a Torus Structure of ∼4 nm Diameter
AR Hale, KA Abboud, G Christou - Inorganic Chemistry, 2023 - ACS Publications
New members of the Mn70 and Mn84 torus-like cluster family have been prepared from a
hybrid comproportionation–alcoholysis reaction of [Mn12O12 (O2CR) 16 (H2O) 4] in alcohol …
hybrid comproportionation–alcoholysis reaction of [Mn12O12 (O2CR) 16 (H2O) 4] in alcohol …
Molecules at the Quantum–Classical Nanoparticle Interface: Giant Mn70 Single-Molecule Magnets of ∼4 nm Diameter
A Vinslava, AJ Tasiopoulos, W Wernsdorfer… - Inorganic …, 2016 - ACS Publications
Two Mn70 torus-like molecules have been obtained from the alcoholysis in EtOH and 2-
ClC2H4OH of [Mn12O12 (O2CMe) 16 (H2O) 4]· 4H2O· 2MeCO2H (1) in the presence of …
ClC2H4OH of [Mn12O12 (O2CMe) 16 (H2O) 4]· 4H2O· 2MeCO2H (1) in the presence of …
High-Spin Mn4 and Mn10 Molecules: Large Spin Changes with Structure in Mixed-Valence MnII4MnIII6 Clusters with Azide and Alkoxide-Based Ligands
TC Stamatatos, KM Poole, KA Abboud… - Inorganic …, 2008 - ACS Publications
The use has been explored of both azide (N3−) and alkoxide-containing groups such as the
anions of 2-(hydroxymethyl) pyridine (hmpH), 2, 6-pyridinedimethanol (pdmH2), 1, 1, 1-tris …
anions of 2-(hydroxymethyl) pyridine (hmpH), 2, 6-pyridinedimethanol (pdmH2), 1, 1, 1-tris …
One-dimensional manganese coordination polymers composed of polynuclear cluster blocks and polypyridyl linkers: Structures and properties
The synthesis, crystal structures and magnetic properties of five new manganese
compounds are reported. These include a linear trinuclear cluster [Mn (II) 3 (O2CCHMe2) 6 …
compounds are reported. These include a linear trinuclear cluster [Mn (II) 3 (O2CCHMe2) 6 …
The use of phosphonates for constructing 3d–4f clusters at high oxidation states: synthesis and characterization of two unusual heterometallic CeMn complexes
The use of phosphonic acids in the synthesis of mixed-metal CeMn complexes has led to the
formation of two phosphonate complexes with unusual topologies:[Ce2Mn6O6 (OH) 5 (t …
formation of two phosphonate complexes with unusual topologies:[Ce2Mn6O6 (OH) 5 (t …
High Nuclearity Single-Molecule Magnets: a Mixed-Valence Mn26 Cluster Containing the Di-2-pyridylketone Diolate Dianion
The employment of the dianion (dpkd2−) of the gem-diol form of di-2-pyridylketone (dpk) as
a tetradentate chelate in manganese chemistry is reported, and the synthesis, crystal …
a tetradentate chelate in manganese chemistry is reported, and the synthesis, crystal …