Development and advancement of iridium (III)-based complexes for photocatalytic hydrogen evolution

DN Tritton, FK Tang, GB Bodedla, FW Lee… - Coordination Chemistry …, 2022 - Elsevier
Among the vast array of transition metal complexes which have been previously reported,
organometallic compounds based on iridium (III) and relevant metal complexes have been …

Recent progress in homogeneous light-driven hydrogen evolution using first-row transition metal catalysts

A Mazzeo, S Santalla, C Gaviglio, F Doctorovich… - Inorganica Chimica …, 2021 - Elsevier
The rich chemistry, low cost and availability offered by first-row transition metals have
inspired many researchers to focus on the design, preparation and testing of a wide plethora …

Precious-Metal-Free CO2 Photoreduction Boosted by Dynamic Coordinative Interaction between Pyridine-Tethered Cu(I) Sensitizers and a Co(II) Catalyst

JW Wang, X Zhang, L Velasco, M Karnahl, Z Li… - JACS Au, 2023 - ACS Publications
Improving the photocatalytic efficiency of a fully noble-metal-free system for CO2 reduction
remains a fundamental challenge, which can be accomplished by facilitating electron …

A Roadmap Towards Visible Light Mediated Electron Transfer Chemistry with Iridium (III) Complexes

R Bevernaegie, SAM Wehlin, B Elias… - …, 2021 - Wiley Online Library
Photo‐induced electron transfer chemistry between molecules is a central theme in several
fields including biology, physics and chemistry. Specifically, in photoredox catalysis, greater …

Improved visible light absorption of potent iridium (III) photo-oxidants for excited-state electron transfer chemistry

R Bevernaegie, SAM Wehlin, EJ Piechota… - Journal of the …, 2020 - ACS Publications
Three iridium photosensitizers,[Ir (dCF3ppy) 2 (N–N)]+, where N–N is 1, 4, 5, 8-
tetraazaphenanthrene (TAP), pyrazino [2, 3-a] phenazine (pzph), or benzo [a] pyrazino [2, 3 …

The odyssey of cobaloximes for catalytic H 2 production and their recent revival with enzyme-inspired design

D Dolui, S Khandelwal, P Majumder… - Chemical …, 2020 - pubs.rsc.org
Cobaloxime complexes gained attention for their intrinsic ability of catalytic H2 production
despite their initial emergence as a vitamin B12 model. The simple, robust, and synthetically …

Coupling of a new porphyrin photosensitizer and cobaloxime cocatalyst for highly efficient photocatalytic H 2 evolution

GB Bodedla, WY Wong, X Zhu - Journal of Materials Chemistry A, 2021 - pubs.rsc.org
Photocatalytic hydrogen evolution (PHE) is a promising strategy to produce environmentally
friendly clean energy with the use of solar power and water. For this, developing an efficient …

Cocatalyst-free photocatalytic hydrogen evolution with simple heteroleptic iridium (III) complexes

GB Bodedla, DN Tritton, X Chen, J Zhao… - ACS Applied Energy …, 2021 - ACS Publications
A simple heteroleptic iridium (III) photosensitizer, Ir-1, containing two ligands 5-
(trifluoromethyl)-2-phenylpyridine (ĈN–CF3) and bipyridine (N̂N) has for the first time …

Synthetic approaches and supramolecular properties of 2, 2′: n′, m ″-terpyridine domains (n= 3, 4, 5, 6; m= 2, 3, 4) based on the 2, 2′-bipyridine core as ligands …

OS Taniya, DS Kopchuk, AF Khasanov… - Coordination Chemistry …, 2021 - Elsevier
Despite almost a century-long history of studying the potential of 2, 2′: 6′, 2 ″-terpyridine
in various fields, the development of synthetic atom-economic “one-pot” approaches …

Fundamental Characterization, Photophysics and Photocatalysis of a Base Metal Iron (II)‐Cobalt (III) Dyad

M Huber‐Gedert, M Nowakowski… - … A European Journal, 2021 - Wiley Online Library
A new base metal iron‐cobalt dyad has been obtained by connection between a
heteroleptic tetra‐NHC iron (II) photosensitizer combining a 2, 6‐bis [3‐(2, 6 …