Reactive p-block cations stabilized by weakly coordinating anions

TA Engesser, MR Lichtenthaler, M Schleep… - Chemical Society …, 2016 - pubs.rsc.org
The chemistry of the p-block elements is a huge playground for fundamental and applied
work. With their bonding from electron deficient to hypercoordinate and formally hypervalent …

Coordination chemistry of homoatomic ligands of bismuth, selenium and tellurium

M Ruck, F Locherer - Coordination Chemistry Reviews, 2015 - Elsevier
Multi-centre-bonds as well as conventional two-centre two-electron bonds are the basis for
charged or uncharged homoatomic molecules of the heavy main-group elements bismuth …

[图书][B] Quaternary alloys based on II-VI semiconductors

V Tomashyk - 2014 - books.google.com
Doped by isovalent or heterovalent foreign impurities, II-VI semiconductor compounds
enable control of optical and electronic properties, making them ideal in detectors, solar …

Controlled synthesis of polyions of heavy main-group elements in ionic liquids

MF Groh, A Wolff, MA Grasser, M Ruck - International Journal of …, 2016 - mdpi.com
Ionic liquids (ILs) have been proven to be valuable reaction media for the synthesis of
inorganic materials among an abundance of other applications in different fields of …

Enhanced water solubility and oral bioavailability of paclitaxel crystal powders through an innovative antisolvent precipitation process: antisolvent crystallization using …

Q Yang, C Zu, W Li, W Wu, Y Ge, L Wang, L Wang, Y Li… - Pharmaceutics, 2020 - mdpi.com
Paclitaxel (PTX) is a poor water-soluble antineoplastic drug with significant antitumor
activity. However, its low bioavailability is a major obstacle for its biomedical applications …

Pentagonal Bismuth Antiprisms with Endohedral Palladium or Platinum Atoms by Low‐Temperature Syntheses

MF Groh, A Wolff, B Wahl, B Rasche… - Zeitschrift für …, 2017 - Wiley Online Library
We present the syntheses, crystal structures, and properties of five metal‐rich salts
containing the Bi104+ pentagonal antiprism with an endohedral palladium or, for the first …

Metal assisted synthesis of cationic sulfidobismuth cubanes in ionic liquids

M Knies, MF Groh, T Pietsch, M Lê Anh… - ChemistryOpen, 2021 - Wiley Online Library
Bi2S3 was dissolved in the presence of either AuCl/PtCl2 or AgCl in the ionic liquids [BMIm]
Cl⋅ xAlCl3 (BMIm= 1‐n‐butyl‐3‐methylimidazolium; x= 4–4.3) through annealing the …

Multi‐Valent Group 14 Chalcogenide Architectures from Ionic Liquids: 0D‐{[Cs@SnII4(GeIV4Se10)4]7−} and 2D‐{[SnII(GeIV4Se10)]2−}

S Santner, A Wolff, M Ruck… - Chemistry–A European …, 2018 - Wiley Online Library
In order to explore if and how salts comprising polycations and salts comprising polyanions
might interact, the [AlBr4]− salt of the [Pt@ Bi10] 4+ cluster cation was added to the reaction …

[P3Se4]+: A Binary Phosphorus–Selenium Cation

KO Feldmann, T Wiegand, J Ren… - … A European Journal, 2015 - Wiley Online Library
Although a fairly large number of binary group 15/16 element cations have been reported,
no example involving phosphorus in combination with a group 16 element has been …

Controlled synthesis of pnicogen–chalcogen polycations in ionic liquids

MF Groh, A Isaeva, U Müller, P Gebauer… - European Journal of …, 2016 - Wiley Online Library
Three new pnicogen–chalcogen polycations were synthesized under specific conditions in
the Lewis‐acidic ionic liquids (ILs)[EMIm] X· nAlX3 and [BMIm] X· nAlX3 (X= Cl, Br;[EMIm]: 1 …