Synthetic chlorins, possible surrogates for chlorophylls, prepared by derivatization of porphyrins

M Taniguchi, JS Lindsey - Chemical reviews, 2017 - ACS Publications
Chlorophylls make Earth green, are the central constituents in the engine of photosynthesis,
and not surprisingly have garnered immense attention. A chlorin, the core chromophore of a …

The Breaking and Mending of meso-Tetraarylporphyrins: Transmuting the Pyrrolic Building Blocks

C Bruckner - Accounts of Chemical Research, 2016 - ACS Publications
Conspectus Naturally occurring porphyrins and hydroporphyrins vary with respect to their
ring substituents and oxidation states, but their tetrapyrrolic frameworks remain fully …

Designing reactivity-based responsive lanthanide probes for multicolor detection in biological systems

E Pershagen, KE Borbas - Coordination Chemistry Reviews, 2014 - Elsevier
Strategies for the design and synthesis of responsive luminescent probes based on
lanthanide complexes are surveyed. The sensitive detection of analytes ranging from ions to …

Synthetic approaches to asymmetric phthalocyanines and their analogues

V Nemykin, S Dudkin, F Dumoulin, C Hirel… - Arkivoc, 2014 - avesis.acibadem.edu.tr
This review summarizes synthetic strategies for the preparation of asymmetric
phthalocyanines and their analogues. Cross-condensation between two phthalonitrile …

Syntheses, structures, modification, and optical properties of meso-tetraaryl-2, 3-dimethoxychlorin, and two isomeric meso-tetraaryl-2, 3, 12, 13 …

LP Samankumara, M Zeller, JA Krause… - Organic & Biomolecular …, 2010 - pubs.rsc.org
The refined syntheses, modification, and first X-ray structural characterization of meso-
tetraarylporphyrin-derived β-tetraolbacteriochlorins are described. These investigations …

Porphyrin macrocycle modification: Pyrrole ring-contracted or-expanded porphyrinoids

LD Costa, JIT Costa, AC Tomé - Molecules, 2016 - mdpi.com
In recent years, several synthetic strategies aiming at the peripheral functionalization of
porphyrins were developed. Particularly interesting are those involving the modification of β …

meso-Arylporpholactones and their Reduction Products

C Brückner, J Ogikubo, JR McCarthy… - The Journal of …, 2012 - ACS Publications
The rational syntheses of meso-tetraaryl-3-oxo-2-oxaporphyrins 5, known as
porpholactones, via MnO4–-mediated oxidations of the corresponding meso-tetraaryl-2, 3 …

meso-Tetraarylporpholactones as high pH sensors

GE Khalil, P Daddario, KSF Lau, S Imtiaz, M King… - Analyst, 2010 - pubs.rsc.org
The ability of meso-tetra (pentafluorophenyl) porpholactone (TFPL) and its Pt (II) complex
[meso-tetra (pentafluorophenyl) porpholactonato] Pt (II)(TFPLPt) to function as optical high …

Fine-tuning of β-substitution to modulate the lowest triplet excited states: A bioinspired approach to design phosphorescent metalloporphyrinoids

XS Ke, H Zhao, X Zou, Y Ning, X Cheng… - Journal of the …, 2015 - ACS Publications
Learning nature's approach to modulate photophysical properties of NIR porphyrinoids by
fine-tuning β-substituents including the number and position, in a manner similar to naturally …

meso-Tetrakis(pentafluorophenyl)porphyrin-Derived Chromene-Annulated Chlorins

MA Hyland, MD Morton… - The Journal of Organic …, 2012 - ACS Publications
The synthesis of mono-and bis-chromene-annulated meso-(pentafluorophenyl) chlorins
from meso-tetrakis (pentafluorophenyl) porphyrins by an OsO4-mediated dihydroxylation …