Transition-metal-catalyzed silylation and borylation of C–H bonds for the synthesis and functionalization of complex molecules

IF Yu, JW Wilson, JF Hartwig - Chemical Reviews, 2023 - ACS Publications
The functionalization of C–H bonds in organic molecules containing functional groups has
been one of the holy grails of catalysis. One synthetically important approach to the diverse …

Planar, curved and twisted molecular nanographenes: Reduction-induced alkali metal coordination

Z Zhou, MA Petrukhina - Coordination Chemistry Reviews, 2023 - Elsevier
Planar and curved polycyclic aromatic hydrocarbons (PAHs) attract significant attention as
molecular models of fullerenes, carbon nanotubes, and graphene, thus stimulating broad …

Saddle-shaped aza-nanographene with multiple odd-membered rings

M Krzeszewski, Ł Dobrzycki, AL Sobolewski… - Chemical …, 2023 - pubs.rsc.org
A saddle-shaped aza-nanographene containing a central 1, 4-dihydropyrrolo [3, 2-b] pyrrole
(DHPP) has been prepared via a rationally designed four-step synthetic pathway …

Schwarzites and Triply Periodic Minimal Surfaces: From Pure Topology Mathematics to Macroscale Applications

LC Felix, R Ambekar, RM Tromer, CF Woellner… - Small, 2024 - Wiley Online Library
Schwarzites are porous (spongy‐like) carbon allotropes with negative Gaussian curvatures.
They are proposed by Mackay and Terrones inspired by the works of the German …

Dibenzotropylium-Capped Orthogonal Geometry Enabling Isolation and Examination of a Series of Hydrocarbons with Multiple 14π-Aromatic Units

Y Hayashi, S Suzuki, T Suzuki… - Journal of the American …, 2023 - ACS Publications
A series of six dications composed of pure hydrocarbons with one to six non-substituted 9,
10-anthrylene units end-capped with two dibenzotropyliums were designed and synthesized …

Hierarchical Self‐Assembly of Curved Aromatics: From Donor–Acceptor Porphyrins to Triply Periodic Minimal Surfaces

S Kumar, T Lis, W Bury, PJ Chmielewski… - Angewandte Chemie …, 2024 - Wiley Online Library
A saddle‐shaped π‐extended zinc porphyrin containing a peripheral pyridyl ligand
undergoes quantitative self‐assembly into a cyclic trimer. The trimer has a prismatic …

Phenine design for nanocarbon molecules

K Ikemoto, TM Fukunaga, H Isobe - … of the Japan Academy, Series B, 2022 - jstage.jst.go.jp
With the name “phenine” given to 1, 3, 5-trisubstituted benzene for a fundamental trigonal
planar unit to weave nanometer-sized networks, a series of curved nanocarbon molecules …

Synthesis of All‐Benzene Multi‐Macrocyclic Nanocarbons by Post‐Functionalization of meta‐Cycloparaphenylenes

JN Gao, A Bu, Y Chen, M Huang… - Angewandte Chemie …, 2024 - Wiley Online Library
Expanding the diversity of multi‐macrocyclic nanocarbons, particularly those with all‐
benzene scaffolds, represents intriguing yet challenging synthetic tasks. Complementary to …

Heteroatom-contained carbon-rich macrocycles and carbon nanobelts: Synthesis, molecular architectures, characteristics and applications

X Sun, J Bai, XY Wang, HY Gong - Coordination Chemistry Reviews, 2024 - Elsevier
Carbon-rich macrocycles and nanobelts have attracted considerable attention for decades
because their aesthetically molecular structures, excellent physical properties, and potential …

Bayesian Inference for Model Analyses of Supramolecular Complexes: A Case Study with Nanocarbon Hosts

Y Onaka, R Sakai, TM Fukunaga… - Angewandte …, 2024 - Wiley Online Library
A 126 π‐electron nanobowl molecule, phenine tridehydrosumanene, was synthesized in 12
steps through the development of a polygon cyclization strategy that assembled the …