Silver‐Based Radical Reactions: Development and Insights

G Fang, X Cong, G Zanoni, Q Liu… - Advanced Synthesis & …, 2017 - Wiley Online Library
Silver‐mediated reactions have recently emerged as a frontier area in organic chemistry.
Indeed, the remarkable property of silver as a single‐electron oxidant has led to its …

Status of biocatalysis in the production of 2, 5-furandicarboxylic acid

D Troiano, V Orsat, MJ Dumont - ACS Catalysis, 2020 - ACS Publications
2, 5-Furandicarboxylic acid (FDCA) is an increasingly important platform chemical that may
be produced via thermochemical, photochemical, electrochemical, or biocatalysis …

Lipase‐mediated selective oxidation of furfural and 5‐hydroxymethylfurfural

M Krystof, M Pérez‐Sánchez… - …, 2013 - Wiley Online Library
Abstract Furfural and 5‐hydroxymethylfurfural (HMF) are important biomass‐derived
platform chemicals that can be obtained from the dehydration of lignocellulosic sugars. A …

Iodine catalyzed oxidation of alcohols and aldehydes to carboxylic acids in water: a metal-free route to the synthesis of furandicarboxylic acid and terephthalic acid

S Hazra, M Deb, AJ Elias - Green Chemistry, 2017 - pubs.rsc.org
A metal-free iodine/NaOH-catalyzed oxidation of alcohols and aldehydes has been
developed for the practical synthesis of a wide range of carboxylic acids using water as the …

Selective depolymerization of lignin towards isolated phenolic acids under mild conditions

W Peng, H Bao, Y Wang, E Cote, WJ Sagues… - …, 2023 - Wiley Online Library
The selective transformation of lignin to value‐added biochemicals (eg, phenolic acids) in
high yields is incredibly challenging due to its structural complexity and many possible …

Salicylic acids as readily available starting materials for the synthesis of meta-substituted biaryls

J Luo, S Preciado, I Larrosa - Chemical Communications, 2015 - pubs.rsc.org
Salicylic acids are shown to be readily available and versatile starting materials that easily
undergo a tandem arylation–protodecarboxylation process under Pd-catalysis. The …

General Method for the Synthesis of Salicylic Acids from Phenols through Palladium‐Catalyzed Silanol‐Directed C H Carboxylation

Y Wang, V Gevorgyan - Angewandte Chemie International …, 2015 - Wiley Online Library
A silanol‐directed, palladium‐catalyzed C H carboxylation reaction of phenols to give
salicylic acids has been developed. This method features high efficiency and selectivity, and …

A biocatalytic method for the chemoselective aerobic oxidation of aldehydes to carboxylic acids

T Knaus, V Tseliou, LD Humphreys, NS Scrutton… - Green …, 2018 - pubs.rsc.org
Herein, we present a study on the oxidation of aldehydes to carboxylic acids using three
recombinant aldehyde dehydrogenases (ALDHs). The ALDHs were used in purified form …

Cu (II)-catalyzed oxidation of sulfides

R Das, D Chakraborty - Tetrahedron Letters, 2010 - Elsevier
A variety of sulfides and disulfides were converted into the corresponding sulfoxide
derivatives with 70% t-BuOOH (water) as the oxidant in the presence of catalytic quantity of …

Harnessing the reactivity of iridium hydrides by air: iridium-catalyzed oxidation of aldehydes to acids in water

Z Yang, R Luo, Z Zhu, X Yang, W Tang - Organometallics, 2017 - ACS Publications
An iridium-catalyzed oxidation of aldehydes to acids was realized by using air as the oxidant
and water as the solvent in the presence of base. Interestingly, the same type of catalysts …