Polymorphism in metal halide perovskites

A Alaei, A Circelli, Y Yuan, Y Yang, SS Lee - Materials Advances, 2021 - pubs.rsc.org
Metal halide perovskites (MHPs) are frontrunners among solution-processable materials for
lightweight, large-area and flexible optoelectronics. These materials, with the general …

[HTML][HTML] The effects of organic cation rotation in hybrid Organic-Inorganic Perovskites: A critical review

S Liu, R Guo, F Xie - Materials & Design, 2022 - Elsevier
The emergence of hybrid organic–inorganic perovskites (HOIPs) has made great progress
in the photovoltaic (PV) field. In recent years, more and more articles have shown that the …

Nucleation-mediated growth of chiral 3D organic–inorganic perovskite single crystals

G Chen, X Liu, J An, S Wang, X Zhao, Z Gu, C Yuan… - Nature Chemistry, 2023 - nature.com
Although their zero-to two-dimensional counterparts are well known, three-dimensional
chiral hybrid organic–inorganic perovskite single crystals have remained difficult because …

Intrinsic dipole arrangement to coordinate energy levels for efficient and stable perovskite solar cells

Y Wu, B Chang, L Wang, H Li, L Pan, Z Liu… - Advanced …, 2023 - Wiley Online Library
Despite great progress in perovskite photovoltaics, it should be noted that the intrinsic
disorder dipolar cations in organic–inorganic hybrid perovskites exert negative effects on the …

Polymorphous nature of cubic halide perovskites

XG Zhao, GM Dalpian, Z Wang, A Zunger - Physical Review B, 2020 - APS
Many common crystal structures can be described by a single (or very few) repeated
structural motif (“monomorphous structures”) such as octahedron in cubic halide perovskites …

Universal dynamics of molecular reorientation in hybrid lead iodide perovskites

DH Fabini, TA Siaw, CC Stoumpos… - Journal of the …, 2017 - ACS Publications
The role of organic molecular cations in the high-performance perovskite photovoltaic
absorbers, methylammonium lead iodide (MAPbI3) and formamidinium lead iodide …

Good vibrations: locking of octahedral tilting in mixed-cation iodide perovskites for solar cells

D Ghosh, P Walsh Atkins, MS Islam, AB Walker… - ACS Energy …, 2017 - ACS Publications
Metal halide perovskite solar cells have rapidly emerged as leading contenders in
photovoltaic technology. Compositions with a mixture of cation species on the A-site show …

Organic cation rotation and immobilization in pure and mixed methylammonium lead-halide perovskites

O Selig, A Sadhanala, C Muller… - Journal of the …, 2017 - ACS Publications
Three-dimensional lead-halide perovskites have attracted a lot of attention due to their
ability to combine solution processing with outstanding optoelectronic properties. Despite …

Universal rules for visible-light absorption in hybrid perovskite materials

M Kato, T Fujiseki, T Miyadera, T Sugita… - Journal of Applied …, 2017 - pubs.aip.org
A variety of organic-inorganic hybrid perovskites (APbX3) consisting of mixed center cations
[A¼CH3NH3 þ, HC (NH2) 2 þ, and Csþ] with different PbX3 À cages (X¼I, Br, and Cl) have …

Entropy-driven stabilization of the cubic phase of MaPbI 3 at room temperature

A Bonadio, CA Escanhoela, FP Sabino… - Journal of Materials …, 2021 - pubs.rsc.org
Methylammonium lead iodide (MAPbI3) is an important light-harvesting semiconducting
material for solar-cell devices. We investigate the effect of long thermal annealing in an inert …