Chemistry of meso-Aryl-Substituted Expanded Porphyrins: Aromaticity and Molecular Twist

T Tanaka, A Osuka - Chemical reviews, 2017 - ACS Publications
Since the discovery of its facile synthesis in 2001, meso-aryl-substituted expanded
porphyrins have been developed as a new class of azaannulenes in light of their facile …

Flexible porphyrinoids

B Szyszko, MJ Białek, E Pacholska-Dudziak… - Chemical …, 2017 - ACS Publications
This review underscores the conformational flexibility of porphyrinoids, a unique class of
functional molecules, starting from the smallest triphyrins (1.1. 1) via [18] porphyrins (1.1 …

Orthogonally aligned cyclic BODIPY arrays with long-lived triplet excited states as efficient heavy-atom-free photosensitizers

Z Zhu, X Zhang, X Guo, Q Wu, Z Li, C Yu, E Hao… - Chemical …, 2021 - pubs.rsc.org
In photosensitizers, long triplet excited state lifetimes are key to their efficient electron
transfer or energy transfer processes. Herein, we report a novel class of cyclic trimeric …

Expandierte Porphyrine: überraschende Strukturen, elektronische Eigenschaften und Reaktivitäten

S Saito, A Osuka - Angewandte Chemie, 2011 - Wiley Online Library
Abstract Die Chemie von expandierten Porphyrinen, den höheren Homologen der
Porphyrine, wurde im Laufe der letzten drei Jahrzehnte ausgiebig untersucht. Expandierte …

3,6-Carbazoylene Octaphyrin (1.0.0.0.1.0.0.0) and Its Bis-BF2 Complex

H Chen, X Shi, Y Lun, Y Xu, T Lu, Z Duan… - Journal of the …, 2022 - ACS Publications
3, 6-Carbazole precursors were used to prepare an octaphyrin. The conformation and
electronic structure of the system could be modulated through trifluoroacetate (TFA) …

Smaragdyrins: emeralds of expanded porphyrin family

Y Pareek, M Ravikanth… - Accounts of Chemical …, 2012 - ACS Publications
Porphyrins are tetrapyrrolic 18 π electron conjugated macrocycles with wide applications
that range from materials to medicine. Expanded porphyrins, synthetic analogues of …

Synthesis and properties of boron porphyrinoids

A Sinha, T Chatterjee, M Ravikanth - Coordination Chemistry Reviews, 2022 - Elsevier
Boron being a small atom, its coordination chemistry with different porphyrinoids is very
unique and unusual compared to coordination chemistry of porphyrinoids with transition …

2, 2′-Bipyrrole-based porphyrinoids

J Setsune - Chemical Reviews, 2017 - ACS Publications
A large number of porphyrinoids containing 2, 2′-bipyrrole subunits have appeared since
they were originally found as a component of sapphyrin and corrole, and it was found that …

Flattened calixarene-like cyclic BODIPY array: a new photosynthetic antenna model

XS Ke, T Kim, VM Lynch, D Kim… - Journal of the American …, 2017 - ACS Publications
A cyclic BODIPY array, characterized by a rigid flattened calixarene-like conformation, acts
as a photosynthetic antenna mimic. The system in question, triBODIPY, is a better antenna …

A new fundamental type of conformational isomerism

PJ Canfield, IM Blake, ZL Cai, IJ Luck, E Krausz… - Nature …, 2018 - nature.com
Isomerism is a fundamental chemical concept, reflecting the fact that the arrangement of
atoms in a molecular entity has a profound influence on its chemical and physical properties …