Conspectus Conversion of common reactants to diverse products is a key objective of
organic syntheses. Recent developments in transition-metal-catalyzed C–H functionalization …

This review describes recent advances in transition-metal-catalyzed C–H functionalization
reactions of pyrazoles to form new C–C and C–heteroatom bonds on the pyrazole ring. In …

Abstract The skeletal presence of 1, 3‐azoles in a variety of bioactive natural products,
pharmacophores, and organic materials demands the derivatization of such heteroarenes …

Alkylpalladium complexes are important intermediates in several industrially relevant
catalytic reactions, such as the Mizoroki–Heck reaction, alkyl C–H activation and ethylene …

The transition metal-catalyzed C–H bond functionalization of azoles has emerged as one of
the most important strategies to decorate these biologically important scaffolds. Despite …

In this contribution we report the synthesis, characterization and in vitro anticancer activity of
novel cyclometalated 4-phenylthiazole-derived ruthenium (II)(2a–e) and osmium (II)(3a–e) …

The efficiency of the formation of C− C bonds under palladium catalysis often depends on
the nature of the carboxylate ligand and carboxylic acids or alkali metal carboxylates …

The mechanochemical, solvent-free Ru (II)-catalyzed alkenylation of N-heteroaryl arenes
with alkynes has been successfully described. A wide spectrum of arenes bearing N …

This review explores the pivotal role of sulfur in advancing sustainable carbon‐carbon (C−
C) coupling reactions. The unique electronic properties of sulfur, as a soft Lewis base with …

Organic compounds, which have vast structural diversity, are heavily decorated with C− H
bonds that differ by carbon hybridization, level of carbon substitution, bond strength …