Challenges and recent advancements in the transformation of CO 2 into carboxylic acids: straightforward assembly with homogeneous 3d metals

R Cauwenbergh, V Goyal, R Maiti, K Natte… - Chemical Society …, 2022 - pubs.rsc.org
The transformation of carbon dioxide (CO2) into useful chemicals, advanced materials, and
energy is a long-standing challenge in both fundamental science and industry. In recent …

Tackling Remote sp3 C−H Functionalization via Ni‐Catalyzed “chain‐walking” Reactions

D Janssen‐Müller, B Sahoo, SZ Sun… - Israel Journal of …, 2020 - Wiley Online Library
Nickel catalysts have recently played an important role for rapidly and reliably converting
feedstock chemicals into valuable compounds of interest for both pharmaceutical and …

Single Electron Transfer-Induced Redox Processes Involving N-(Acyloxy)phthalimides

SK Parida, T Mandal, S Das, SK Hota, S De Sarkar… - ACS …, 2021 - ACS Publications
The past decade has witnessed the emergence of N-(acyloxy) phthalimides (NHPI esters)
and its derivatives at the forefront of synthetic methods facilitating the construction of diverse …

Metal‐Free Electrochemical Carboxylation of Organic Halides in the Presence of Catalytic Amounts of an Organomediator

Y Wang, Z Zhao, D Pan, S Wang, K Jia… - Angewandte Chemie …, 2022 - Wiley Online Library
Herein, an electroreductive carboxylation of organic carbon‐halogen bonds (X= Br and Cl)
promoted by catalytic amounts of naphthalene as an organic mediator is reported. This …

Photoinduced hydrocarboxylation via thiol-catalyzed delivery of formate across activated alkenes

SN Alektiar, ZK Wickens - Journal of the American Chemical …, 2021 - ACS Publications
Herein we disclose a new photochemical process to prepare carboxylic acids from formate
salts and alkenes. This redox-neutral hydrocarboxylation proceeds in high yields across …

Homogeneous Catalysis for the Conversion of CO2, CO, CH3OH, and CH4 to C2+ Chemicals via C–C Bond Formation

SA Fors, CA Malapit - ACS Catalysis, 2023 - ACS Publications
In the past few decades, the advances of CO2 reduction have been mostly focused on the
synthesis of C1 products, such as CO, formic acid, methanol, and methane. However, the …

Kinetically-Controlled Ni-Catalyzed Direct Carboxylation of Unactivated Secondary Alkyl Bromides without Chain Walking

J Davies, JR Lyonnet, B Carvalho… - Journal of the …, 2024 - ACS Publications
Herein, we report the direct carboxylation of unactivated secondary alkyl bromides enabled
by the merger of photoredox and nickel catalysis, a previously inaccessible endeavor in the …

α-Amino Acids and Peptides as Bifunctional Reagents: Carbocarboxylation of Activated Alkenes via Recycling CO2

LL Liao, GM Cao, YX Jiang, XH Jin, XL Hu… - Journal of the …, 2021 - ACS Publications
Carboxylic acids, including amino acids (AAs), have been widely used as reagents for
decarboxylative couplings. In contrast to previous decarboxylative couplings that release …

Nickel-catalyzed reductive carboxylation and amidation reactions

A Tortajada, M Borjesson, R Martin - Accounts of Chemical …, 2021 - ACS Publications
Conspectus The ubiquity and importance of carboxylic acids and amides in peptides,
pharmaceuticals, agrochemicals, and synthetic materials has challenged chemists to design …

Late-stage carbon-14 labeling and isotope exchange: emerging opportunities and future challenges

V Babin, F Taran, D Audisio - JACS Au, 2022 - ACS Publications
Carbon-14 (14C) is a gold standard technology routinely utilized in pharmaceutical and
agrochemical industries for tracking synthetic organic molecules and providing their …