Beyond structural motifs: the frontier of actinide-containing metal–organic frameworks

CR Martin, GA Leith, NB Shustova - Chemical Science, 2021 - pubs.rsc.org
In this perspective, we feature recent advances in the field of actinide-containing metal–
organic frameworks (An-MOFs) with a main focus on their electronic, catalytic …

Mining for Metal–Organic Systems: Chemistry Frontiers of Th-, U-, and Zr-Materials

KC Park, J Lim, GC Thaggard… - Journal of the American …, 2024 - ACS Publications
The conceptual framework presented in this Perspective overviews the design principles of
innovative thorium-based materials that could address urgent needs of the medicinal …

Examination of structure and bonding in 10-coordinate europium and americium terpyridyl complexes

FD White, AN Gaiser, EJ Warzecha… - Inorganic …, 2018 - ACS Publications
M (TpyNO2)(NO3) 3 (H2O)· THF (M= La, Nd, Sm, Eu, Tb, Am; TpyNO2= 4′-nitrophenyl
terpyridyl) have been prepared from the reaction of M (NO3) 3· n H2O with TpyNO2 in THF …

A semiconducting uranium–organic framework based on a tetrathiafulvalene derivative

F Zhai, H Li, D Gui, C Xia, Z Chai, S Wang - Dalton Transactions, 2022 - pubs.rsc.org
A rare case of semiconducting actinide-based metal–organic framework SCU-125 was
designed and synthesized. As a result of the lack of two coordination sites in the plane of the …

Redox and Coordination Chemistry Differences of the 4f and 5f Elements

FD White - 2018 - search.proquest.com
This dissertation seeks to determine the differences in the lanthanides and later actinides in
non-aqueous media. Research in the f-elements is significantly understudied compared to …

Exploring Unique Bonding Behavior in the f-Block

AN Gaiser - 2020 - diginole.lib.fsu.edu
Two important applications of the f elements lie in the separation of the components
comprising spent nuclear fuel, and f element use as radionuclides in nuclear medicine. Two …