Redox‐active BIAN‐based Diimine Ligands in Metal‐Catalyzed Small Molecule Syntheses

J Bernauer, J Pölker, A Jacobi von Wangelin - ChemCatChem, 2022 - Wiley Online Library
Abstract α‐Diimine ligands have significantly shaped the coordination chemistry of most
transition metal complexes. Among them, bis (imino) acenaphthene ligands (BIANs) have …

Heteroleptic Pd (II) and Pt (II) Complexes with Redox-Active Ligands: Synthesis, Structure, and Multimodal Anticancer Mechanism

NF Romashev, PA Abramov, IV Bakaev… - Inorganic …, 2022 - ACS Publications
A series of heteroleptic square-planar Pt and Pd complexes with bis (diisopropylphenyl)
iminoacenaphtene (dpp-Bian) and Cl, 1, 3-dithia-2-thione-4, 5-dithiolate (dmit), or 1, 3-dithia …

Effects of bis (imino) acenaphthene (bian)-derived ligands on the cytotoxicity, DNA interactions, and redox activity of palladium (II) bipyridine complexes

VI Komlyagina, NF Romashev… - Inorganic …, 2023 - ACS Publications
A series of heteroleptic bipyridine Pd (II) complexes based on 1, 2-bis [(2, 6-
diisopropylphenyl) imino] acenaphthene (dpp-Bian) or 1, 2-bis [(2, 4, 6-trimethylphenyl) …

Advances in the chemistry of redox-active bis (imino) acenaphthenes (BIAN): A case of transition metal complexes

IS Fomenko, NF Romashev, AL Gushchin - Coordination Chemistry …, 2024 - Elsevier
The chemistry of redox-active bis (imino) acenaphthenes (BIAN, R-bian) and metal
complexes based on them has been a rapidly developing field since the 1990s. The key …

Novel Copper (II) Complexes with BIAN Ligands: Synthesis, Structure and Catalytic Properties of the Oxidation of Isopropylbenzene

IS Fomenko, OS Koshcheeva, NI Kuznetsova… - Catalysts, 2023 - mdpi.com
Two new isomeric complexes [CuBr2 (R-bian)](R= 4-Me-Ph (1), 2-Me-Ph (2)) were obtained
by reacting copper (II) bromide with 1, 2-bis [(2-methylphenyl) imino] acenaphthene ligands …

Syntheses, characterization, and catalytic potential of novel vanadium and molybdenum Schiff base complexes for the preparation of benzimidazoles, benzoxazoles …

H Kargar, K Kargar, M Fallah-Mehrjardi… - Monatshefte für Chemie …, 2021 - Springer
A new ONO-tridentate Schiff base ligand (H2L) derived from 3-methoxysalicylaldehyde and
nicotinic hydrazide was synthesized and characterized by elemental analysis, FT-IR, 1H …

Design and molecular docking studies of {N1-[2-(amino)ethyl]ethane-1,2-diamine}-[tris(oxido)]-molybdenum(VI) complex as a potential antivirus drug: from synthesis …

S Kumar, M Choudhary - Journal of Coordination Chemistry, 2023 - Taylor & Francis
The aim of this study was to synthesize and examine the molecular docking of a Mo (VI)
complex [Mo (dien) O3](1),{N1-[2-(amino) ethyl] ethane-1, 2-diamine}-[tris (oxido)] …

Copper (II) complexes with BIAN-type ligands: Synthesis and catalytic activity in oxidation of hydrocarbons and alcohols

IS Fomenko, MI Gongola, LS Shul'pina… - Inorganica Chimica …, 2024 - Elsevier
A series of copper (II) complexes of general formula [Cu (R-bian) X 2](X= Cl, Br)(1–5)
containing rare and/or hard-to-get BIAN ligands with Ph, 4-OH-Ph, 3-NH 2-Py and 3-Py …

Electrochemical and mechanistic study of oxidative degradation of favipiravir by electrogenerated superoxide through proton-coupled electron transfer

T Nakayama, R Honda - ACS omega, 2021 - ACS Publications
Electrochemical analyses aided by density functional theory calculations were used to
investigate the oxidative degradation of pyrazine antiviral drugs, 3-hydroxypyrazine-2 …

General Access to Acenaphthene-Fused N-Heterocyclic Carbene Ligands

S Redl, D Timelthaler, P Sunzenauer, K Faust… - …, 2023 - ACS Publications
We communicate a general method for the syntheses of acenaphthene-fused imidazolinium
salts that are direct precursors to augmented N-heterocyclic carbenes with a fixed cis …