Nitroxides, also known as nitroxyl radicals, are long-lived or stable radicals with the general
structure R1R2N–O•. The spin distribution over the nitroxide N and O atoms contributes to …

Recent advances in synthetic methodologies for selective, oxidative transformations using
Bobbitt's salt (4-acetamido-2, 2, 6, 6-tetramethyl-1-oxopiperidinium tetrafluoroborate, 1) and …

A range of acyl azoles have been prepared from aromatic, heteroaromatic, and aliphatic
aldehydes by means of an oxidative amidation reaction. The methodology employs a …

A protocol for the oxidation of alcohols to aldehydes and ketones employing an
electrochemical aminoxyl-mediated reaction is presented. The approach employs a catalytic …

Nitroxide‐Catalyzed Oxidative Amidation of Aldehydes to Yield N‐Acyl Azoles Using
Sodium Persulfate - Politano - 2022 - European Journal of Organic Chemistry - Wiley Online …

A methodology for the preparation of nitriles from aldehydes by means of an oxidative
functionalisation reaction is reported. It employs ammonium persulfate as both the primary …

An efficient and straightforward procedure for the synthesis of HFIP esters-containing 2H-
benzopyrans has been established through palladium-catalyzed one-pot cyclization …

A methodology for the oxidation of α-trifluoromethyl alcohols to the corresponding
trifluoromethyl ketones is presented. A catalytic quantity of a nitroxide is used, and …

Background: Oxidation is a valuable tool in preparative organic chemistry. Oxoammonium
salts and nitroxides have proven valuable as reagents and catalysts in this endeavor …

This work investigates various key oxidation and oxidative functionalization reactions that
occur using a bench-stable nitroxide and its oxoammonium nitrate salt congener. Such …