Prior to the year 2000, non‐aqueous uranium chemistry mainly involved metallocene and
classical alkyl, amide, or alkoxide compounds as well as established carbene, imido, and …

A critical review on the mechanisms and behavior of 4f intraconfigurational transitions in
controllable chemical environments related to nonradiative intramolecular energy transfer …

Terminal uranium oxido, sulfido, and selenido metallocenes were synthesized, and their
reactivity was comprehensively studied. Heating of an equimolar mixture of [η5-1, 2, 4 …

The successful management and safe disposal of high-level nuclear waste necessitate the
efficient separation of actinides (An) from lanthanides (Ln), which has emerged as a crucial …

Improved versions of the segmented all-electron relativistically contracted (SARC) basis sets
for the lanthanides are presented. The second-generation SARC2 basis sets maintain …

This chapter reviews the reaction chemistry of uranium complexes with small molecules of
industrial and biological importance. Specifically, carbon monoxide (CO), nitrogen monoxide …

Lead has been used as a heavy atom derivative to solve the phase problem in the crystal
structures of a variety of protein including the calcium proteins calmodulin and …

Our knowledge of actinide chemical bonds lags far behind our understanding of the bonding
regimes of any other series of elements. This is a major issue given the technological as well …

A break in periodicity occurs in the actinide series between plutonium and americium as the
result of the localization of 5 f electrons. The subsequent chemistry of later actinides is …

Separation of trivalent actinides (An (III)) and lanthanides (Ln (III)) poses a huge challenge in
the reprocessing of spent nuclear fuel due to their similar chemical properties. N, N …