This review is an update on tris (trimethylsilyl) silane, TTMSS, in organic chemistry, focusing
on the advancements of the past decade. The overview includes a wide range of chemical …

Deuterated organic compounds have widespread applications in many fields such as
medicinal chemistry, mechanistic studies, and quantitative analyses. Traditionally, the …

The amino imidazolin-2-imine ligand [HAmIm, 1, 2-(DippNH)–C6H4–N═ C (N i PrCMe) 2] is
employed in the synthesis of the paramagnetic cobalt (I) arene complex Co (AmIm)(η 6 …

Isotopically labeled compounds are highly desirable as they can serve as both mechanistic
probes in chemistry and diagnostic tools in medicinal research. Herein, we report an …

The unsymmetrical amino-imidazolin-2-imine ligand [HAmIm, 1, 2-(DippNH)–C6H4–N= C (N
i PrCMe) 2] is employed in the synthesis of the iron (I) arene complex [(AmIm) Fe (η 6 …

A copper-catalyzed reduction of alkynes to alkanes and deuterated alkanes is described
under transfer hydrogenation and transfer deuteration conditions. Commercially available …

A synthetic study into the catalytic hydrogen/deuterium (H/D) exchange of 1° silanes, 2°
silanes, and 3° siloxanes is presented, facilitated by iron-β-diketiminato complexes (1a and …

Organosilanes possessing an enantioenriched stereogenic silicon center are important in
many branches of chemistry, yet they remain challenging to synthesize in a practical and …

Pinacolborane, catecholborane, triethylsilane, triphenylsilane, dimethylphenylsilane, 1, 1, 1,
3, 5, 5, 5-heptamethyltrisiloxane, triethylgermane, triphenylgermane, and triphenylstannane …

A series of ruthenium nanoparticles (Ru· MIC) stabilized with different mesoionic 1, 2, 3-
triazolylidene (MIC) ligands were prepared by decomposition of the Ru (COD)(COT)(COD …