[HTML][HTML] The known-unknowns of anomalous underscreening in concentrated electrolytes

GR Elliott, KP Gregory, H Robertson, VSJ Craig… - Chemical Physics …, 2024 - Elsevier
Electrolytes are central to life and technology but lack complete understanding. Recent
experiments with highly concentrated electrolytes have revealed electrostatic decay lengths …

New Electrical Conductivity Model for Electrolyte Solutions Based on the Debye–Hückel–Onsager Theory

S Naseri Boroujeni, B Maribo-Mogensen… - The Journal of …, 2023 - ACS Publications
A new electrical conductivity model is developed for unassociated electrolyte solutions
based on the Debye–Hückel–Onsager theory. In this model, we assume that a single …

On analytical theories for conductivity and self-diffusion in concentrated electrolytes

O Bernard, M Jardat, B Rotenberg… - The Journal of Chemical …, 2023 - pubs.aip.org
Describing analytically the transport properties of electrolytes, such as their conductivity or
the self-diffusion of the ions, has been a central challenge of chemical physics for almost a …

Novel model for predicting the electrical conductivity of multisalt electrolyte solutions

S Naseri Boroujeni, B Maribo-Mogensen… - The Journal of …, 2024 - ACS Publications
This study presents a novel model to predict the electrical conductivity of multisalt electrolyte
solutions by incorporating corrections to the ideal behavior due to relaxation and …

Electrical noise in electrolytes: a theoretical perspective

J Kim, G Pireddu, I Chubak, S Nair, B Rotenberg - Faraday …, 2023 - pubs.rsc.org
Seemingly unrelated experiments such as electrolyte transport through nanotubes, nano-
scale electrochemistry, NMR relaxometry and surface force balance measurements, all …

Perspective: New directions in dynamical density functional theory

M Te Vrugt, R Wittkowski - Journal of Physics: Condensed Matter, 2022 - iopscience.iop.org
Classical dynamical density functional theory (DDFT) has become one of the central
modeling approaches in nonequilibrium soft matter physics. Recent years have seen the …

Temporal response of the conductivity of electrolytes

H Bonneau, V Démery, E Raphaël - Journal of Statistical …, 2023 - iopscience.iop.org
We study the temporal response of the electric current in an electrolyte under a sudden
switch on or switch off of an external electric field of arbitrary magnitude. We use Stochastic …

[HTML][HTML] Correlation-induced viscous dissipation in concentrated electrolytes

P Robin - The Journal of Chemical Physics, 2024 - pubs.aip.org
Electrostatic correlations between ions dissolved in water are known to impact their transport
properties in numerous ways, from conductivity to ion selectivity. The effects of these …

Stochastic density functional theory for ions in a polar solvent

P Illien, A Carof, B Rotenberg - arXiv preprint arXiv:2407.17232, 2024 - arxiv.org
In recent years, the theoretical description of electrical noise and fluctuation-induced effects
in electrolytes has gained a renewed interest, enabled by stochastic field theories like …

Frequency-Dependent Conductivity of Concentrated Electrolytes: A Stochastic Density Functional Theory

H Bonneau, Y Avni, D Andelman, H Orland - arXiv preprint arXiv …, 2024 - arxiv.org
The response of ionic solutions to time-varying electric fields, quantified by a frequency-
dependent conductivity, is essential in many electrochemical applications. Yet, it constitutes …