A new electrical conductivity model is developed for unassociated electrolyte solutions based on the Debye–Hückel–Onsager theory. In this model, we assume that a single …
O Bernard, M Jardat, B Rotenberg… - The Journal of Chemical …, 2023 - pubs.aip.org
Describing analytically the transport properties of electrolytes, such as their conductivity or the self-diffusion of the ions, has been a central challenge of chemical physics for almost a …
This study presents a novel model to predict the electrical conductivity of multisalt electrolyte solutions by incorporating corrections to the ideal behavior due to relaxation and …
Seemingly unrelated experiments such as electrolyte transport through nanotubes, nano- scale electrochemistry, NMR relaxometry and surface force balance measurements, all …
M Te Vrugt, R Wittkowski - Journal of Physics: Condensed Matter, 2022 - iopscience.iop.org
Classical dynamical density functional theory (DDFT) has become one of the central modeling approaches in nonequilibrium soft matter physics. Recent years have seen the …
We study the temporal response of the electric current in an electrolyte under a sudden switch on or switch off of an external electric field of arbitrary magnitude. We use Stochastic …
P Robin - The Journal of Chemical Physics, 2024 - pubs.aip.org
Electrostatic correlations between ions dissolved in water are known to impact their transport properties in numerous ways, from conductivity to ion selectivity. The effects of these …
P Illien, A Carof, B Rotenberg - arXiv preprint arXiv:2407.17232, 2024 - arxiv.org
In recent years, the theoretical description of electrical noise and fluctuation-induced effects in electrolytes has gained a renewed interest, enabled by stochastic field theories like …
The response of ionic solutions to time-varying electric fields, quantified by a frequency- dependent conductivity, is essential in many electrochemical applications. Yet, it constitutes …