Chiral supramolecular polymers

F García, R Gómez, L Sánchez - Chemical Society Reviews, 2023 - pubs.rsc.org
As an active branch within the field of supramolecular polymers, chiral supramolecular
polymers (SPs) are an excellent benchmark to generate helical structures that can clarify the …

Bottom-up supramolecular assembly in two dimensions

I Insua, J Bergueiro, A Méndez-Ardoy… - Chemical …, 2022 - pubs.rsc.org
The self-assembly of molecules in two dimensions (2D) is gathering attention from all
disciplines across the chemical sciences. Attracted by the interesting properties of two …

Pathway complexity in supramolecular copolymerization and blocky star copolymers by a hetero-seeding effect

P Khanra, AK Singh, L Roy, A Das - Journal of the American …, 2023 - ACS Publications
This study unravels the intricate kinetic and thermodynamic pathways involved in the
supramolecular copolymerization of the two chiral dipolar naphthalene monoimide (NMI) …

Pathway and length control of supramolecular polymers in aqueous media via a hydrogen bonding lock

I Helmers, G Ghosh, RQ Albuquerque… - Angewandte Chemie …, 2021 - Wiley Online Library
Programming the organization of π‐conjugated systems into nanostructures of defined
dimensions is a requirement for the preparation of functional materials. Herein, we have …

Crystallization‐Driven Controlled Two‐Dimensional (2D) Assemblies from Chromophore‐Appended Poly (L‐lactide) s: Highly Efficient Energy Transfer on a 2D …

A Rajak, A Das - Angewandte Chemie International Edition, 2022 - Wiley Online Library
A rational approach towards precision two‐dimensional (2D) assemblies by crystallization‐
driven self‐assembly (CDSA) of poly (L‐lactides)(PLLAs), end‐capped with dipolar dyes like …

Controlled supramolecular polymerization of π-systems

G Ghosh, P Dey, S Ghosh - Chemical Communications, 2020 - pubs.rsc.org
Supramolecular polymers, albeit having precise internal order, largely lack precision in the
mesoscopic scale because in most examples supramolecular polymerization occurs under …

Dual trapping of a metastable planarized triarylborane π-system based on folding and lewis acid–base complexation for seeded polymerization

H Choi, S Ogi, N Ando… - Journal of the American …, 2021 - ACS Publications
We report the kinetically controlled supramolecular polymerization of boron-containing π-
conjugated molecules, which was enabled by a seeding method based on dual trapping of a …

Living supramolecular polymerization of fluorinated cyclohexanes

O Shyshov, SV Haridas, L Pesce, H Qi, A Gardin… - Nature …, 2021 - nature.com
The development of powerful methods for living covalent polymerization has been a key
driver of progress in organic materials science. While there have been remarkable reports …

Tweaking a BODIPY Spherical Self‐Assembly to 2D Supramolecular Polymers Facilitates Excited‐State Cascade Energy Transfer

G Das, S Cherumukkil, A Padmakumar… - Angewandte Chemie …, 2021 - Wiley Online Library
Excited state properties such as emission, exciton transport, electron transfer, etc., are
strongly dependent on the shape, size and molecular arrangement of chromophore based …

Unravelling denaturation, temperature and cosolvent-driven chiroptical switching in peptide self-assembly with switchable piezoelectric responses

A Ramesh, TN Das, TK Maji, G Ghosh - Chemical Science, 2024 - pubs.rsc.org
Herein, we explore the intricate pathway complexity, focusing on the dynamic interplay
between kinetic and thermodynamic states, during the supramolecular self-assembly of …