Driving polymer brushes from synthesis to functioning

R Wang, Q Wei, W Sheng, B Yu, F Zhou… - Angewandte …, 2023 - Wiley Online Library
The great success of controlled radical polymerizations has encouraged researchers to
develop more facile and robust approaches for surface‐initiated polymerizations (SIPs) to …

Tailoring polymer dispersity and shape of molecular weight distributions: methods and applications

R Whitfield, NP Truong, D Messmer, K Parkatzidis… - Chemical …, 2019 - pubs.rsc.org
The width and shape of molecular weight distributions can significantly affect the properties
of polymeric materials and thus are key parameters to control. This mini-review aims to …

Recent developments in antimicrobial and antifouling coatings to reduce or prevent contamination and cross‐contamination of food contact surfaces by bacteria

W DeFlorio, S Liu, AR White, TM Taylor… - … Reviews in Food …, 2021 - Wiley Online Library
Illness as the result of ingesting bacterially contaminated foodstuffs represents a significant
annual loss of human quality of life and economic impact globally. Significant research …

Dual-functional, superhydrophobic coatings with bacterial anticontact and antimicrobial characteristics

S Liu, J Zheng, L Hao, Y Yegin, M Bae… - … applied materials & …, 2020 - ACS Publications
Bacterial pathogens are responsible for millions of cases of illnesses and deaths each year
throughout the world. The development of novel surfaces and coatings that effectively inhibit …

Precise control of both dispersity and molecular weight distribution shape by polymer blending

R Whitfield, NP Truong, A Anastasaki - Angewandte Chemie, 2021 - Wiley Online Library
The breadth and the shape of molecular weight distributions can significantly influence
fundamental polymer properties that are critical for various applications. However, current …

Opportunities, challenges, and pitfalls in making, characterizing, and understanding polymer brushes

CW Pester, HA Klok, EM Benetti - Macromolecules, 2023 - ACS Publications
Polymer brushes have been theoretically described, their behavior under diverse conditions
has been modeled, and their preparation via surface-initiated polymerizations (SIPs) has …

Shaping the structure and response of surface-grafted polymer brushes via the molecular weight distribution

JC Conrad, ML Robertson - JACS Au, 2023 - ACS Publications
Breadth in the molecular weight distribution is an inherent feature of synthetic polymer
systems. While in the past this was typically considered as an unavoidable consequence of …

FRET‐integrated polymer brushes for spatially resolved sensing of changes in polymer conformation

QA Besford, H Yong, H Merlitz… - Angewandte Chemie …, 2021 - Wiley Online Library
Polymer brush surfaces that alter their physical properties in response to chemical stimuli
have the capacity to be used as new surface‐based sensing materials. For such surfaces …

Benchtop Preparation of Polymer Brushes by SI-PET-RAFT: The Effect of the Polymer Composition and Structure on Inhibition of a Pseudomonas Biofilm

G Ng, M Li, J Yeow, K Jung, CW Pester… - ACS Applied Materials …, 2020 - ACS Publications
We report a high-throughput method for producing surface-tethered polymeric brushes on
glass substrates via surface-initiated photoinduced electron transfer-reversible addition …

Dispersity within brushes plays a major role in determining their interfacial properties: The case of oligoxazoline-based graft polymers

M Romio, B Grob, L Trachsel, A Mattarei… - Journal of the …, 2021 - ACS Publications
Many synthetic polymers used to form polymer-brush films feature a main backbone with
functional, oligomeric side chains. While the structure of such graft polymers mimics …