This review highlights and summarizes various optically active porphyrin and
phthalocyanine molecules prepared using a wide range of structural modification methods …

Electronic structures and direct observation of adlayers on Au (111) of triangular expanded
hemiporphyrazines that can be classified into azaporphyrinoids and which can trap three …

Expanded porphyrins are large-cavity macrocycles with enormous potential in coordination
chemistry, anion sensing, photodynamic therapy, and optoelectronics. In the last two …

Hemihexaphyrazines can be considered as hexamembered porphyrinoids of the ABABAB
type, where thiadiazole rings (A) and pyrrole-containing subunits (B) joined via aza bridges …

The complexation of high-spin lanthanides to porphyrinoids is a powerful strategy for the
development of advanced molecular magnets. In this context, the use of expanded …

Reduction of free-base trithiadodecaazahexaphyrin, H3Hhp, by potassium graphite in the
presence of cobalt (II) acetylacetonate and cryptand [2.2. 2] produces {Cryptand [2.2. 2](K+)} …

First chiral bornane [2, 3-b] pyrazino-fused [30] trithiadodecaazahexaphyrins were prepared
by a crossover condensation of R-(+)-or S-(–)-bornane [2′, 3′-b]-2, 3-dicyanopyrazine …

The gas-phase molecular structure of the unsubstituted [30] trithia-2, 3, 5, 10, 12, 13, 15, 20,
22, 23, 25, 30-dodecaazahexaphyrin (C30H15N15S3) has been studied by a synchronous …

New substituted [30] trithiadodecaazahexaphyrines (hemihexaphyrazines) were
synthesized by a crossover condensation of 2, 5-diamino-1, 3, 4-thiadiazole with 4-chloro-5 …

Abstract Deprotonation of free-base [30] trithia-2, 3, 5, 10, 12, 13, 15, 20, 22, 23, 25, 30-
dodecaazahexaphyrin (hemihexaphyrazine, H 3 Hhp) and 5, 10, 15-triphenylcorrole (H 3 …