From stable radicals to thermally robust high-spin diradicals and triradicals

C Shu, Z Yang, A Rajca - Chemical Reviews, 2023 - ACS Publications
Stable radicals and thermally robust high-spin di-and triradicals have emerged as important
organic materials due to their promising applications in diverse fields. New fundamental …

Hyperpolarized water via dissolution dynamic nuclear polarization: Applications in biomolecular NMR

Y Lee, J Kim - Applied Spectroscopy Reviews, 2024 - Taylor & Francis
Although traditional nuclear magnetic resonance (NMR) spectroscopy is essential for
investigating the structures and dynamics of biomolecules, it is impeded by low sensitivity …

Redox Transformations of the OX063 Radical in Biological Media: Oxidative Decay of Initial Trityl with Further Formation of Structurally‐Modified TAM

SS Ovcherenko, AE Raizvich… - … A European Journal, 2024 - Wiley Online Library
Being a low‐toxic and hydrophilic representative of TAM, OX063 has shown its suitability for
in‐vivo and in‐cell EPR experiments and design of spin labels. Using 13C labeling, we …

Synthesis and dark state EPR properties of PDI‐trityl dyads and triads

K Kopp, L Westhofen, T Hett… - … A European Journal, 2024 - Wiley Online Library
Covalently‐linked chromophore‐radical systems with their unique optical and magnetic
properties are useful for applications in, eg, quantum information science. To expand the …

Solid Effect Dynamic Nuclear Polarization Enhancement of> 500 at 9.4 T

R Wei, Y Rao, A Venkatesh… - The Journal of Physical …, 2024 - ACS Publications
Efficient polarizing agents for dynamic nuclear polarization (DNP) enhanced magic angle
spinning (MAS) NMR spectroscopy are of high current interest due to the potential to …

13C Hyperpolarization of Viscous Liquids by Transfer of Solid-Effect 1H Dynamic Nuclear Polarization at High Magnetic Field

D Dai, V Denysenkov, EG Bagryanskaya… - The Journal of …, 2023 - ACS Publications
Dynamic nuclear polarization (DNP) is routinely used as a method for increasing the
sensitivity to nuclear magnetic resonance (NMR). Recently, high-field solid-effect DNP in …

[HTML][HTML] Structure and ion transport properties of organic ionic compounds revealed by NMR

H Zhu - Magnetic Resonance Letters, 2024 - Elsevier
Organic ionic plastic crystals (OIPCs) are emerging as an important material family for solid-
state electrolytes and many other applications. They have significant advantages over …

[HTML][HTML] The solid effect of dynamic nuclear polarization in liquids – accounting for -tensor anisotropy at high magnetic fields

D Sezer, D Dai, TF Prisner - Magnetic Resonance, 2023 - mr.copernicus.org
In spite of its name, the solid effect of dynamic nuclear polarization (DNP) is also operative in
viscous liquids, where the dipolar interaction between the polarized nuclear spins and the …

Nuclear spin relaxation

MCD Tayler - 2024 - books.rsc.org
This chapter explores current theoretical and experimental trends in nuclear spin relaxation,
providing a digest of around 100 research papers published between 2022 and mid 2023 …

CHEMISTRY FOR SUSTAINABLE DEVELOPMENT

AE RAIZVIKH, KA LOMANOVICH, O ROGOZHNIKOVA… - CHEMISTRY, 2023 - elibrary.ru
In the recent years, triarylmethyl radicals are widely used as spin probes and tags, so the
study of their properties is of great interest. In the present work, the magnetic resonance …