Chlorinated solvents: their advantages, disadvantages, and alternatives in organic and medicinal chemistry

A Jordan, P Stoy, HF Sneddon - Chemical Reviews, 2020 - ACS Publications
Chlorinated Solvents: Their Advantages, Disadvantages, and Alternatives in Organic and
Medicinal Chemistry | Chemical Reviews ACS ACS Publications C&EN CAS Find my …

Transition Metal-Free, Methoxide-Catalyzed Synthesis of Pyridoindolones

S Park, JU Park, YL Kim, JH Kim - The Journal of Organic …, 2021 - ACS Publications
A simple transition metal-free strategy for the synthesis of pyrido [1, 2-a] indolone derivatives
has been devised through sodium methoxide-catalyzed intramolecular cyclization of 2 …

Efficient nucleophilic degradation of an organophosphorus pesticide “diazinon” mediated by green solvents and microwave heating

D Millán, RA Tapia, P Pavez - Frontiers in Chemistry, 2019 - frontiersin.org
An efficient strategy for the degradation of organophosphate pesticide Diazinon was
investigated. In this work, ionic liquids, bio-based solvents, and two conventional organic …

Aromatic Substitution

MR Crampton - … Reaction Mechanisms· 2017: An annual survey …, 2020 - Wiley Online Library
Summary This Chapter Contains Sections titled: Introduction General Nucleophilic
Substitution The S NAr Mechanism Meisenheimer and Related Complexes Benzyne and …

Single‐Electron Transfer in σ‐Complexation Reactions of 2, 6‐Dimethoxy‐3, 5‐dinitropyridine with Para‐X‐phenoxide Anions in Aqueous Solution

F Mahdhaoui, N Dhahri… - International Journal of …, 2016 - Wiley Online Library
Second‐order rate constants have been measured spectrophotometrically for reactions of 2,
6‐dimethoxy‐3, 5‐dinitropyridine 1 with 4‐X‐substituted phenoxide anions (X= OMe, Me, H …

Regioselective quinazoline C2 modifications through the azide–tetrazole tautomeric equilibrium

DD Līpiņš, A Jeminejs, U Ušacka… - Beilstein Journal of …, 2024 - beilstein-journals.org
Chloro-4-sulfonylquinazolines undergo functional group swap when treated with an azide
nucleophile: 1) the azide replaces the sulfonyl group at the C4 position; 2) the intrinsic azide …

Nucleofugality hierarchy, in the aminolysis reaction of 4-cyanophenyl 4-nitrophenyl carbonate and thionocarbonate. Experimental and theoretical study

R Montecinos, ME Aliaga, P Pavez, P Cornejo… - New Journal of …, 2021 - pubs.rsc.org
Nucleophilic substitution reactions of the title compounds have been investigated with a
series of secondary alicyclic amines in several solvents. The solvent, amine, and …

[图书][B] Organic Reaction Mechanisms: 2013

AC Knipe, MG Moloney - 2016 - Wiley Online Library
The present volume, the forty-ninth in the series, surveys research on organic reaction
mechanisms described in the available literature dated 2013. In order to limit the size of the …

Kinetic study on pyridinolysis of aryl benzenesulfonates: factors governing regioselectivity and reaction mechanism

IH Um, YJ Jung, JM Dust - Canadian Journal of Chemistry, 2022 - cdnsciencepub.com
A kinetic study is reported for reactions of 2, 4-dinitrophenyl X-substituted-
benzenesulfonates (1a–1f) and Y-substituted-phenyl benzenesulfonates (2a–2f) with Z …

Nucleophilic aromatic substitution in chlorinated aromatic systems with a glutathione thiolate model

DW Boerth, AC Arvanites - Journal of Physical Organic …, 2017 - Wiley Online Library
The conjugation of glutathione with chlorobenzene and di‐, tri‐, tetra‐, and hexa‐chlorinated
benzenes via nucleophilic aromatic substitution was modeled for isolated reacting species …