The intramolecular C–H borylation of (hetero) arenes and alkenes using electrophilic
boranes is a powerful transition metal free methodology for forming C–B bonds. These C–H …

Highly electrophilic boron species that borylate arenes are generated by halide abstraction
from CatBX (Cat= catecholato, C6H4O22−, X= Cl or Br) by [Et3Si][CbBr6](CbBr6=[closo-1-H …

Borazine-doped π-conjugated frameworks have significantly contributed to advancing the
application of boron–nitrogen-doped organic materials. However, the challenging synthetic …

Helicenes are chiral polycyclic aromatic hydrocarbons (PAHs) of significant interest, eg in
supramolecular chemistry, materials science and asymmetric catalysis. Herein an enhanced …

The first examples of borylation under conditions of borenium ion generation from hydrogen-
bridged boron cations are described. The observable H-bridged cations are generated by …

The chapter “Atropisomerism and axial chirality in heteroaromatic compounds” provides a
summary of the present knowledge of this important topic. The structure of the chapter is: first …

(© Cío),(@ B2C58),(@ N2C58),(@ BNC58),(@ C12B24N24), and (@ B30N3o) are
studied. The heats of formation of such 60-atom systems from benzene, naphthalene, and …

A new class of highly porous borazine-linked polymers (BLPs) has been synthesized
utilizing arylamines and boron trihalides. BLPs exhibit Brunauer–Emmett–Teller (BET) …

Boron-doped organic compounds display unique properties as a result of the presence of an
empty p orbital on boron and the ability to switch between a trigonal planar and a tetrahedral …

We have defined a procedure for the late‐stage functionalization of aryl borazines to
facilitate the synthesis of a diverse array of borazine derivatives with varying substitution …