Single-molecule magnets beyond a single lanthanide ion: the art of coupling

YC Chen, ML Tong - Chemical Science, 2022 - pubs.rsc.org
The promising future of storing and processing quantized information at the molecular level
has been attracting the study of Single-Molecule Magnets (SMMs) for almost three decades …

Lanthanide SMMs based on belt macrocycles: Recent advances and general trends

Y Gil, A Castro‐Alvarez, P Fuentealba… - … A European Journal, 2022 - Wiley Online Library
Enhancement of axial magnetic anisotropy is the central objective to push forward the
performance of Single‐Molecule Magnet (SMM) complexes. In the case of mononuclear …

Emerging trends on designing high-performance dysprosium (III) single-molecule magnets

TG Ashebr, H Li, X Ying, XL Li, C Zhao, S Liu… - ACS Materials …, 2022 - ACS Publications
The present prospect of single-molecule magnets (SMMs) research is more appealing after
the detection of magnetic remanence above liquid-nitrogen temperatures. From the current …

Isolation of a bent dysprosium bis (amide) single-molecule magnet

J Emerson-King, GK Gransbury… - Journal of the …, 2024 - ACS Publications
The isolation of formally two-coordinate lanthanide (Ln) complexes is synthetically
challenging, due to predominantly ionic Ln bonding regimes favoring high coordination …

Photo‐responsive Single‐Molecule Magnet Showing 0D to 1D Single‐Crystal‐to‐Single‐Crystal Structural Transition and Hysteresis Modulation

XD Huang, XF Ma, LM Zheng - … Chemie International Edition, 2023 - Wiley Online Library
Photo‐responsive lanthanide‐based single‐molecule magnets (SMM) hold great promise
for future switching and memory devices. Herein, we report a dysprosium phosphonate [DyIII …

Impact of Ligand Substituents on the Magnetization Dynamics of Mononuclear DyIII Single-Molecule Magnets

M Wang, Y Guo, Z Han, X Cheng, YQ Zhang… - Inorganic …, 2022 - ACS Publications
Two mononuclear DyIII single-molecule magnets with different ligand substituents located
far from the coordinating atoms,[Dy (L-NO2)(NO3)](1) and [Dy (L-Me)(NO3)](2), and their …

A new breakthrough in low-coordinate Dy (III) single-molecule magnets

Z Zhu, X Ying, C Zhao, YQ Zhang… - Inorganic Chemistry …, 2022 - pubs.rsc.org
Low-coordinate lanthanide (Ln) complexes have attracted considerable attention in the field
of molecular magnetism by virtue of their excellent potential in constructing high …

Pseudo-mono-axial ligand fields that support high energy barriers in triangular dodecahedral Dy (III) single-ion magnets

B Zhang, Z Cheng, Y Wu, L Chen, R Jing, X Cai… - Chemical …, 2022 - pubs.rsc.org
The synthesis of air-stable, high-performance single-molecule magnets (SMMs) is of great
significance for their practical applications. Indeed, Ln complexes with high coordination …

Bis‐Alkoxide Dysprosium (III) Crown Ether Complexes Exhibit Tunable Air Stability and Record Energy Barrier

WJ Xu, QC Luo, ZH Li, YQ Zhai, YZ Zheng - Advanced Science, 2024 - Wiley Online Library
High‐performance and air‐stable single‐molecule magnets (SMMs) can offer great
convenience for the fabrication of information storage devices. However, the controversial …

Synthesis, structure, and zero-field SMM behavior of homometallic Dy2, Dy4, and Dy6 complexes

P Kumar, A Swain, J Acharya, Y Li, V Kumar… - Inorganic …, 2022 - ACS Publications
The synthesis, structure, and magnetic properties of three DyIII complexes of different
nuclearity,[Dy2 (H2L) 2 (NO3)][NO3]· 2H2O· CH3OH (1),[Dy4 (HL) 2 (piv) 4 (OH) 2](2), and …