C–H activation has surfaced as an increasingly powerful tool for molecular sciences, with
notable applications to material sciences, crop protection, drug discovery, and …

The chemistry of vanadium has seen remarkable activity in the past 50 years. In the present
review, reactions catalyzed by homogeneous and supported vanadium complexes from …

Oxidative aromatic coupling occupies a fundamental place in the modern chemistry of
aromatic compounds. It is a method of choice for the assembly of large and bewildering …

Conspectus Axially chiral compounds with rotationally constrained σ-bonds that exhibit
atropisomerism are lucrative synthetic targets because of their ubiquity in functional …

Phenols and their derivatives are the elementary building blocks for several classes of
complex molecules that play essential roles in biological systems. Nature has devised …

We have developed an efficient modular asymmetric synthesis of azahelicenes through an
organocatalyzed asymmetric multicomponent reaction from readily available polycyclic …

Helicenes and helicene‐like molecules, usually containing multiple ortho‐fused aromatic
rings, possess unique helical chirality. These compounds have found a wide range of …

Catalytic enantioselective synthesis of chiral helicenes and helicenoids has emerged as an
important area of research. In the efforts toward efficient and enantioselective synthesis of …

Heterohelicenes are of increasing importance in the fields of materials science, molecular
recognition, and asymmetric catalysis. However, enantioselective construction of these …

A novel type of chiral redox disulfonate iron complex for asymmetric catalysis is reported.
The [Fe ((R a)-BINSate)]+(BINSate= 1, 1′-binaphthalene-2, 2′-disulfonate) complex …