A Paradigm Shift in Catalysis: Electro-and Photomediated Nickel-Catalyzed Cross-Coupling Reactions

MD Palkowitz, MA Emmanuel… - Accounts of Chemical …, 2023 - ACS Publications
Conspectus Transition-metal catalyzed cross-coupling reactions are fundamental reactions
in organic chemistry, facilitating strategic bond formations for accessing natural products …

The golden age of thermally activated delayed fluorescence materials: design and exploitation

JM Dos Santos, D Hall, B Basumatary… - Chemical …, 2024 - ACS Publications
Since the seminal report by Adachi and co-workers in 2012, there has been a veritable
explosion of interest in the design of thermally activated delayed fluorescence (TADF) …

Imidazophenothiazine-Based Thermally Activated Delayed Fluorescence Materials with Ultra-Long-Lived Excited States for Energy Transfer Photocatalysis

R Hojo, K Bergmann, SA Elgadi… - Journal of the …, 2023 - ACS Publications
Triplet-triplet energy transfer (EnT) is a powerful activation pathway in photocatalysis that
unlocks new organic transformations and improves the sustainability of organic synthesis …

Rejuvenation of dearomative cycloaddition reactions via visible light energy transfer catalysis

A Palai, P Rai, B Maji - Chemical Science, 2023 - pubs.rsc.org
Dearomative cycloaddition is a powerful technique to access sp3-rich three-dimensional
structural motifs from simple flat, aromatic feedstock. The building-up of unprecedentedly …

Enantioselective Intramolecular ortho Photocycloaddition Reactions of 2‐Acetonaphthones

P Yan, S Stegbauer, Q Wu… - Angewandte Chemie …, 2024 - Wiley Online Library
Acetonaphthones, which bear an alkenyl group tethered to its C1 carbon atom via an
oxygen atom, were found to undergo an enantioselective intramolecular ortho …

Heptazine‐Based TADF Materials for Nanoparticle‐Based Nonlinear Optical Bioimaging

DM Mayder, R Hojo, WL Primrose… - Advanced Functional …, 2022 - Wiley Online Library
Abstract s‐Heptazines are emerging as strong electron acceptors for efficient thermally
activated delayed fluorescent (TADF) materials, yet the difficulties in synthesizing them have …

Sterically Encumbered Heteroleptic Copper (I) β-Diketiminate Complexes with Extended Excited-State Lifetimes

D Kim, MC Rosko, VQ Dang, FN Castellano… - Inorganic …, 2023 - ACS Publications
One of the main challenges in developing effective copper (I) photosensitizers is their short
excited-state lifetimes, usually attributed to structural distortion upon light excitation. We …

Thermally activated delayed fluorescence sensitizers as organic and green alternatives in energy-transfer photocatalysis

R Hojo, AM Polgar, ZM Hudson - ACS Sustainable Chemistry & …, 2022 - ACS Publications
Photocatalysis has captured the imagination of synthetic chemists and is poised to become
a staple of the fine chemical industry. Over the past decade, the subfield of energy-transfer …

Modulation of Delayed Fluorescence Guided by Conformational Effect-Mediated Thermally Enhanced Phosphorescence in Phenothiazines–Quinoline–Cl Conjugates

S Dey, AK Pal, M Upadhyay, A Datta… - The Journal of Physical …, 2023 - ACS Publications
Triplet energy harvesting via thermally activated delayed fluorescence (TADF) from pure
organic systems has attracted great attention in organic light-emitting diodes, sensing, and …

Bifunctional organic photocatalysts for enantioselective visible-light-mediated photocatalysis

AB Rolka, B König - Nature Synthesis, 2023 - nature.com
This Review aims to highlight the developments in the field of visible-light-mediated
enantioselective photocatalysis utilizing bifunctional organic photocatalysts by giving an …