Coordination of anions by noncovalently bonded σ-hole ligands

S Scheiner, M Michalczyk, W Zierkiewicz - Coordination Chemistry Reviews, 2020 - Elsevier
Research on σ-hole interactions that include halogen, chalcogen, pnicogen, and tetrel
bonding has been accelerating in recent years. These cousins of the H-bond have many …

Crystal engineering strategies towards halogen-bonded metal–organic multi-component solids: Salts, cocrystals and salt cocrystals

V Nemec, K Lisac, N Bedeković, L Fotović… - …, 2021 - pubs.rsc.org
Over the past several decades, halogen bonding has become a standard 'tool'in
supramolecular chemistry and particularly in crystal engineering. Traditionally, the study of …

Reactivity of acyclic diaminocarbene ligands

MA Kinzhalov, KV Luzyanin - Coordination Chemistry Reviews, 2019 - Elsevier
Acyclic diaminocarbenes (ADCs) are powerful ligands with a broad application scope in
organometallic chemistry, catalysis, photophysics and crystal engineering. Although the …

Dramatically Enhanced Solubility of Halide‐Containing Organometallic Species in Diiodomethane: The Role of Solvent⋅⋅⋅ Complex Halogen Bonding

MA Kinzhalov, MV Kashina, AS Mikherdov… - Angewandte …, 2018 - Wiley Online Library
In the current study, we evaluated the solubility of a number of organometallic species and
showed that it is noticeably improved in diiodomethane when compared to other haloalkane …

Electrophilic–nucleophilic dualism of nickel (II) toward Ni··· I noncovalent interactions: Semicoordination of iodine centers via electron belt and halogen bonding via σ …

ZM Bikbaeva, DM Ivanov, AS Novikov… - Inorganic …, 2017 - ACS Publications
The nitrosoguanidinate complex [Ni {NH C (NMe2) NN (O)} 2](1) was cocrystallized with I2
and sym-trifluorotriiodobenzene (FIB) to give associates 1· 2I2 and 1· 2FIB. Structures of …

A novel family of polyiodo‐bromoantimonate (III) complexes: cation‐driven self‐assembly of photoconductive metal‐polyhalide frameworks

SA Adonin, LI Udalova, PA Abramov… - … A European Journal, 2018 - Wiley Online Library
In the presence of different cations, reactions of [SbBr6] 3− and I2 result in a new family of
diverse supramolecular 1D polyiodide‐bromoantimonate networks. The coordination …

Metal-Involving Bifurcated Halogen Bonding C–Br···η2(Cl–Pt)

U Dabranskaya, DM Ivanov, AS Novikov… - Crystal Growth & …, 2018 - ACS Publications
The complexes trans-[PtCl2 (NCNR2) 2](R2= Me2 1, Et2 2,(CH2) 4 3) were cocrystallized
with CBr4 in CHCl3 (1 and 3) or in MeNO2 (2) forming adducts 1· CHCl3· CBr4, 2· 2CBr4 …

Dihalomethanes as bent bifunctional XB/XB‐Donating building blocks for construction of metal‐involving halogen bonded hexagons

MV Kashina, MA Kinzhalov, AS Smirnov… - Chemistry–An Asian …, 2019 - Wiley Online Library
Abstract The dihalomethanes CH2X2 (X= Cl, Br, I) were co‐crystallized with the isocyanide
complexes trans‐[MXM2 (CNC6H4‐4‐XC) 2](M= Pd, Pt; XM= Br, I; XC= F, Cl, Br) to give an …

Pt/Pd and I/Br isostructural exchange provides formation of C–I··· Pd, C–Br··· Pt, and C–Br··· Pd metal-involving halogen bonding

SV Baykov, U Dabranskaya, DM Ivanov… - Crystal Growth & …, 2018 - ACS Publications
Complexes trans-[MCl2 (NCNMe2) 2](M= Pt 1, Pd 2) were cocrystallized with CHBr3 and
CHI3, forming 1: 2 adducts isomorphic with previously reported trans-[PtCl2 (NCNMe2) 2] …

Halobismuthates with halopyridinium cations: Appearance or non-appearance of unusual colouring

SA Adonin, ID Gorokh, AS Novikov, DG Samsonenko… - …, 2018 - pubs.rsc.org
A series of chloro-and bromobismuthate complexes with bromopyridinium cations was
prepared and characterized by XRD analysis and diffuse reflectance spectroscopy. In one …