Porphyrins at interfaces

W Auwärter, D Écija, F Klappenberger, JV Barth - Nature chemistry, 2015 - nature.com
Porphyrins and other tetrapyrrole macrocycles possess an impressive variety of functional
properties that have been exploited in natural and artificial systems. Different metal centres …

Self-assembly of metal–organic coordination structures on surfaces

L Dong, ZA Gao, N Lin - Progress in Surface Science, 2016 - Elsevier
Metal–organic coordination structures are materials comprising reticular metal centers and
organic linkers in which the two constituents bind with each other via metal–ligand …

Ferromagnetism on an atom-thick & extended 2D metal-organic coordination network

J Lobo-Checa, L Hernández-López, MM Otrokov… - Nature …, 2024 - nature.com
Ferromagnetism is the collective alignment of atomic spins that retain a net magnetic
moment below the Curie temperature, even in the absence of external magnetic fields …

Mimicking enzymatic active sites on surfaces for energy conversion chemistry

R Gutzler, S Stepanow, D Grumelli… - Accounts of chemical …, 2015 - ACS Publications
Metal–organic supramolecular chemistry on surfaces has matured to a point where its
underlying growth mechanisms are well understood and structures of defined coordination …

Room‐Temperature on‐spin‐switching and tuning in a porphyrin‐based multifunctional interface

HM Sturmeit, I Cojocariu, A Windischbacher… - Small, 2021 - Wiley Online Library
Molecular interfaces formed between metals and molecular compounds offer a great
potential as building blocks for future opto‐electronics and spintronics devices. Here, a …

On-Surface Synthesis: A New Route Realizing Single-Layer Conjugated Metal–Organic Structures

J Liu, M Abel, N Lin - The Journal of Physical Chemistry Letters, 2022 - ACS Publications
Recently, both experimental and theoretical advances have demonstrated that two-
dimensional conjugated metal–organic frameworks (2D-cMOFs) exhibit interesting …

Origin of the Magnetic Exciton in the van der Waals Antiferromagnet

T Klaproth, S Aswartham, Y Shemerliuk, S Selter… - Physical Review Letters, 2023 - APS
An ultrasharp photoluminescence line intimately related to antiferromagnetic order has been
found in NiPS 3, a correlated van der Waals material, opening prospects for magneto-optical …

Emergence of Band Structure in a Two-Dimensional Metal–Organic Framework upon Hierarchical Self-Assembly

D Baranowski, M Thaler, D Brandstetter… - ACS …, 2024 - ACS Publications
Two-dimensional metal–organic frameworks (2D-MOFs) represent a category of atomically
thin materials that combine the structural tunability of molecular systems with the crystalline …

Frustration enhanced by Kitaev exchange in a triangular antiferromagnet

C Wellm, W Roscher, J Zeisner, A Alfonsov, R Zhong… - Physical Review B, 2021 - APS
Triangular Heisenberg antiferromagnets are prototypes of geometric frustration, even if for
nearest-neighbor interactions quantum fluctuations are not usually strong enough to destroy …

Manipulating the electronic and magnetic properties of coordinated nickel atoms in metal–organic frameworks by hydrogenation

B Liu, G Miao, W Zhong, X Huang, N Su, J Guo… - ACS …, 2022 - ACS Publications
In the pursuit of manipulating the properties of single atoms, the surface-supported metal–
organic frameworks (MOFs) provide us opportunities to individually address the electronic …