[HTML][HTML] Quantifying mass-dependent isotope fractionation and nuclear field shift effects for the light rare Earth elements in hydrous systems

M Nestmeyer, AJ McCoy-West - Geochimica et Cosmochimica Acta, 2025 - Elsevier
The improving sensitivity of mass-spectrometers has opened the potential of using stable
isotope signatures of the rare Earth elements (REE) as geochemical tracers. However, thus …

A Chromatographic Approach for High-Precision Eu Isotope Analysis

H Wu, JH Bai, XR Liang, XB Lu, YN Deng, M Li… - Analytical …, 2024 - ACS Publications
Eu isotopes are promising tracers across various scientific domains such as planetary, earth,
and marine science, yet their high-precision analysis has been challenging due to the …

High-precision stable isotope measurements of tungsten and molybdenum in single sample aliquots combined with optimized separation for mixed double spikes

T Kashiwabara, Y Fukami, S Kubo… - Journal of Analytical …, 2024 - pubs.rsc.org
A key driver to develop stable tungsten (W) isotope geochemistry is its unique relationship
with molybdenum (Mo). Here, we establish a combined double-spike (DS) method for W …

Cerium Stable Isotopic Composition of Non-Carbonaceous Chondrites

H Pourkhorsandi, V Debaille… - ACS Earth and Space …, 2024 - ACS Publications
The elemental and isotopic compositions of the rare earth elements (REE) reveal critical
information about the physicochemical dynamics of the solar nebula. Cerium (Ce) is the …

High-Precision Measurement of Eu Isotopes Enabled by Nd Internal Normalization

H Wu, J Bai, X Liang, XB Lu, YY Li, Y Deng… - Journal of Analytical …, 2025 - pubs.rsc.org
Eu isotopes are recognized as potential indicators for understanding continental crust
evolution, ocean circulation, and rare earth element mineralization. However, methods for …

Progress and Prospect of Rare Earth Elements Stable Isotope Analysis Techniques

X Lu, J Bai, F Ye, G Wei - Journal of Earth Science, 2024 - Springer
Rare earth elements (REEs) are integral to geochemical tracing systems due to their unique
geochemical properties. Their distribution patterns, fractionation, anomalies, and radio …

[HTML][HTML] Optimization of separation and MC-ICP-MS methods for determining Eu isotopic ratios in Si-and Ba-rich fractionated igneous rocks and other natural materials

SG Lee - Spectrochimica Acta Part B: Atomic Spectroscopy, 2024 - Elsevier
Eu isotope ratio can be precisely measured by MC-ICP-MS using a Sm isotope pair as spike
for normalization. The standard chemical reagent NIST3117a exhibits almost no Eu isotope …

Nuclear volume and mass dependent fractionation of cerium isotopes

EA Schauble - Geochemical Journal, 2024 - jstage.jst.go.jp
Equilibrium cerium isotope fractionations in cerium-bearing minerals and aqueous species
are estimated using electronic structure calculations that include both nuclear volume and …

Characterisation of δ142Ce/140Ce Isotope Ratios in Geological Reference Materials using an SSB+Sm Doping and MC‐ICP‐MS Method

J Wu, Y An, X Li, F Liu, J Xu, M Ling… - Geostandards and … - Wiley Online Library
We report the δ142/140Ce values for thirty‐three widely available geological reference
materials (RMs), including igneous rocks, metamorphic rocks, sediments and soils. The Ce …