Visible light-induced transition metal catalysis

KPS Cheung, S Sarkar, V Gevorgyan - Chemical reviews, 2021 - ACS Publications
In recent years, visible light-induced transition metal catalysis has emerged as a new
paradigm in organic photocatalysis, which has led to the discovery of unprecedented …

Metallaphotoredox: the merger of photoredox and transition metal catalysis

AY Chan, IB Perry, NB Bissonnette, BF Buksh… - Chemical …, 2021 - ACS Publications
The merger of photoredox catalysis with transition metal catalysis, termed
metallaphotoredox catalysis, has become a mainstay in synthetic methodology over the past …

Chiral photocatalyst structures in asymmetric photochemical synthesis

MJ Genzink, JB Kidd, WB Swords, TP Yoon - Chemical reviews, 2021 - ACS Publications
Asymmetric catalysis is a major theme of research in contemporary synthetic organic
chemistry. The discovery of general strategies for highly enantioselective photochemical …

Photoredox-catalyzed C–H functionalization reactions

N Holmberg-Douglas, DA Nicewicz - Chemical reviews, 2021 - ACS Publications
The fields of C–H functionalization and photoredox catalysis have garnered enormous
interest and utility in the past several decades. Many different scientific disciplines have …

Metal stereogenicity in asymmetric transition metal catalysis

PS Steinlandt, L Zhang, E Meggers - Chemical Reviews, 2023 - ACS Publications
Chiral transition metal catalysts represent a powerful and economic tool for implementing
stereocenters in organic synthesis, with the metal center providing a strong chemical …

Visible light photocatalysis in the late-stage functionalization of pharmaceutically relevant compounds

R Cannalire, S Pelliccia, L Sancineto… - Chemical Society …, 2021 - pubs.rsc.org
The late stage functionalization (LSF) of complex biorelevant compounds is a powerful tool
to speed up the identification of structure–activity relationships (SARs) and to optimize …

Transition metal-catalyzed organic reactions under visible light: recent developments and future perspectives

WM Cheng, R Shang - ACS Catalysis, 2020 - ACS Publications
The development of transition metal (TM) catalysis for organic synthesis under visible light
without recourse to typical photoredox catalysts has become a rapidly growing area of …

The persistent radical effect in organic synthesis

D Leifert, A Studer - Angewandte Chemie International Edition, 2020 - Wiley Online Library
Radical–radical couplings are mostly nearly diffusion‐controlled processes. Therefore, the
selective cross‐coupling of two different radicals is challenging and not a synthetically …

Modular access to chiral α-(hetero) aryl amines via Ni/photoredox-catalyzed enantioselective cross-coupling

X Shu, D Zhong, Y Lin, X Qin, H Huo - Journal of the American …, 2022 - ACS Publications
Chiral α-aryl N-heterocycles are commonly found in natural products, pharmaceutical
agents, and chiral catalysts but remain challenging to access via asymmetric catalysis …

Enantioselective radical addition to ketones through Lewis acid-enabled photoredox catalysis

L Hou, Y Zhou, H Yu, T Zhan, W Cao… - Journal of the American …, 2022 - ACS Publications
Photocatalysis opens up a new window for carbonyl chemistry. Despite a multitude of
photochemical reactions of carbonyl compounds, visible light-induced catalytic asymmetric …