An initial review (PCET1) on proton-coupled electron transfer (PCET) by Huynh and Meyer appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …
At the core of many important energy conversion processes in chemistry and biology are oxidation-reduction reactions in which both electrons and protons are transferred. An …
Photosystem II (PSII), a multisubunit pigment–protein supercomplex found in cyanobacteria, algae, and plants, catalyzes a unique reaction in nature: the light-driven oxidation of water …
DJ Vinyard, GW Brudvig - Annual review of physical chemistry, 2017 - annualreviews.org
The active site of photosynthetic water oxidation is the oxygen-evolving complex (OEC) in the photosystem II (PSII) reaction center. The OEC is a Mn4CaO5 cluster embedded in the …
YV Geletii, B Botar, P Kogerler, DA Hillesheim… - Angewandte …, 2008 - academia.edu
The design of viable and well-defined molecular catalysts for water oxidation in conjunction with the conversion of solar into chemical energy is both intellectually and practically …
N Cox, J Messinger - Biochimica Et Biophysica Acta (BBA)-Bioenergetics, 2013 - Elsevier
This brief article aims at presenting a concise summary of all experimental findings regarding substrate water-binding to the Mn 4 CaO 5 cluster in photosystem II. Mass …
In the last 10 years, a number of advances have been made in the study of the oxygen- evolving complex (OEC) of photosystem II (PSII). Along with this new understanding of the …
Water binding to the Mn4O5Ca cluster of the oxygen-evolving complex (OEC) of Photosystem II (PSII) poised in the S2 state was studied via H217O-and 2H2O-labeling and …
KJ Young, BJ Brennan, R Tagore… - Accounts of chemical …, 2015 - ACS Publications
Conspectus Catalysts for light-driven water oxidation are a critical component for development of solar fuels technology. The multielectron redox chemistry required for this …