Water oxidation in photosystem II

W Lubitz, M Chrysina, N Cox - Photosynthesis research, 2019 - Springer
Biological water oxidation, performed by a single enzyme, photosystem II, is a central
research topic not only in understanding the photosynthetic apparatus but also for the …

Proton-coupled electron transfer

DR Weinberg, CJ Gagliardi, JF Hull, CF Murphy… - Chemical …, 2012 - ACS Publications
An initial review (PCET1) on proton-coupled electron transfer (PCET) by Huynh and Meyer
appeared in Chemical Reviews in 2007.(1) This is a follow-up on the original. It was …

Proton-coupled electron transfer

MHV Huynh, TJ Meyer - Chemical Reviews, 2007 - ACS Publications
At the core of many important energy conversion processes in chemistry and biology are
oxidation-reduction reactions in which both electrons and protons are transferred. An …

Biological water oxidation

N Cox, DA Pantazis, F Neese… - Accounts of chemical …, 2013 - ACS Publications
Photosystem II (PSII), a multisubunit pigment–protein supercomplex found in cyanobacteria,
algae, and plants, catalyzes a unique reaction in nature: the light-driven oxidation of water …

Progress toward a molecular mechanism of water oxidation in photosystem II

DJ Vinyard, GW Brudvig - Annual review of physical chemistry, 2017 - annualreviews.org
The active site of photosynthetic water oxidation is the oxygen-evolving complex (OEC) in
the photosystem II (PSII) reaction center. The OEC is a Mn4CaO5 cluster embedded in the …

[PDF][PDF] An all-inorganic, stable, and highly active tetraruthenium homogeneous catalyst for water oxidation

YV Geletii, B Botar, P Kogerler, DA Hillesheim… - Angewandte …, 2008 - academia.edu
The design of viable and well-defined molecular catalysts for water oxidation in conjunction
with the conversion of solar into chemical energy is both intellectually and practically …

[HTML][HTML] Reflections on substrate water and dioxygen formation

N Cox, J Messinger - Biochimica Et Biophysica Acta (BBA)-Bioenergetics, 2013 - Elsevier
This brief article aims at presenting a concise summary of all experimental findings
regarding substrate water-binding to the Mn 4 CaO 5 cluster in photosystem II. Mass …

Functional models for the oxygen-evolving complex of photosystem II

CW Cady, RH Crabtree, GW Brudvig - Coordination chemistry reviews, 2008 - Elsevier
In the last 10 years, a number of advances have been made in the study of the oxygen-
evolving complex (OEC) of photosystem II (PSII). Along with this new understanding of the …

Detection of the Water-Binding Sites of the Oxygen-Evolving Complex of Photosystem II Using W-Band 17O Electron–Electron Double Resonance-Detected NMR …

L Rapatskiy, N Cox, A Savitsky, WM Ames… - Journal of the …, 2012 - ACS Publications
Water binding to the Mn4O5Ca cluster of the oxygen-evolving complex (OEC) of
Photosystem II (PSII) poised in the S2 state was studied via H217O-and 2H2O-labeling and …

Photosynthetic water oxidation: insights from manganese model chemistry

KJ Young, BJ Brennan, R Tagore… - Accounts of chemical …, 2015 - ACS Publications
Conspectus Catalysts for light-driven water oxidation are a critical component for
development of solar fuels technology. The multielectron redox chemistry required for this …