[HTML][HTML] Side-group switching between metal-to-ligand charge-transfer and metal-centered excited state properties in iron (II) N-heterocyclic carbene complexes
Fe (II) N-heterocyclic carbene (NHC) complexes have emerged over the last decade as a
promising class of light-harvesting complexes for a variety of photochemical applications …
promising class of light-harvesting complexes for a variety of photochemical applications …
Time-Resolved X-ray Emission Spectroscopy and Synthetic High-Spin Model Complexes Resolve Ambiguities in Excited-State Assignments of Transition-Metal …
To fully harness the potential of abundant metal coordination complex photosensitizers, a
detailed understanding of the molecular properties that dictate and control the electronic …
detailed understanding of the molecular properties that dictate and control the electronic …
Iron (III) Carbene Complexes with Tunable Excited State Energies for Photoredox and Upconversion
J Wellauer, F Ziereisen, N Sinha… - Journal of the …, 2024 - ACS Publications
Substituting precious elements in luminophores and photocatalysts by abundant first-row
transition metals remains a significant challenge, and iron continues to be particularly …
transition metals remains a significant challenge, and iron continues to be particularly …
Beyond the First Coordination Sphere─ Manipulating the Excited-State Landscape in Iron (II) Chromophores with Protons
K Witas, SS Nair, T Maisuradze, L Zedler… - Journal of the …, 2024 - ACS Publications
Molecular transition metal chromophores play a central role in light harvesting and energy
conversion. Recently, earth-abundant transition-metal-based chromophores have begun to …
conversion. Recently, earth-abundant transition-metal-based chromophores have begun to …
Inverse Problems in Pump–Probe Spectroscopy
DS Tikhonov, D Garg, M Schnell - Photochem, 2024 - mdpi.com
Ultrafast pump–probe spectroscopic studies allow for deep insights into the mechanisms
and timescales of photophysical and photochemical processes. Extracting valuable …
and timescales of photophysical and photochemical processes. Extracting valuable …
Photoactive Iron N-Heterocyclic Carbene Complexes: From Design to Photoredox Catalysis
J Schwarz - 2024 - portal.research.lu.se
Recent years have seen a surge to develop first-row transition metal complexes with
photophysics and photochemistry similar to those of noble metals, such as ruthenium and …
photophysics and photochemistry similar to those of noble metals, such as ruthenium and …
Effect of Ligand Modification on Properties of Iron-Tetracarbene Photosensitisers: Design, Synthesis and Photovoltaic Applications
S Persson - 2024 - portal.research.lu.se
The use of N-heterocyclic carbenes in conjunction with iron has been studied over the last
decade for the purpose of achieving well-functioning iron-based photosensitisers. This is …
decade for the purpose of achieving well-functioning iron-based photosensitisers. This is …