Ultrastable glasses: new perspectives for an old problem

C Rodriguez-Tinoco, M Gonzalez-Silveira… - La Rivista del Nuovo …, 2022 - Springer
Ultrastable glasses (mostly prepared from the vapor phase under optimized deposition
conditions) represent a unique class of materials with low enthalpies and high kinetic …

Surface dynamics of glasses

H Tian, Q Xu, H Zhang, RD Priestley, B Zuo - Applied Physics Reviews, 2022 - pubs.aip.org
Two challenging scientific disciplines, ie, the physics of glasses [Anderson, Science 267,
1615 (1995); Kennedy and Norman, Science 309, 75 (2005)] and interface chemistry …

Intramolecular dynamic coupling slows surface relaxation of polymer glasses

H Tian, J Luo, Q Tang, H Zha, RD Priestley… - Nature …, 2024 - nature.com
Over the past three decades, studies have indicated a mobile surface layer with steep
gradients on glass surfaces. Among various glasses, polymers are unique because …

[HTML][HTML] Physical aging in molecular glasses beyond the α relaxation

V Di Lisio, VM Stavropoulou… - The Journal of Chemical …, 2023 - pubs.aip.org
The description of kinetics of physical aging, namely the slow evolution of a glass
thermodynamic state toward equilibrium, generally relies on the exclusive role of the main α …

Cracking the Kauzmann paradox

RS Welch, ED Zanotto, CJ Wilkinson, DR Cassar… - Acta Materialia, 2023 - Elsevier
The Kauzmann paradox and associated Kauzmann temperature are two of the most widely
debated topics in glass science over the past eighty years. Both conceptualized by Walter …

Size-dependent vitrification in metallic glasses

V Di Lisio, I Gallino, SS Riegler, M Frey… - Nature …, 2023 - nature.com
Reducing the sample size can profoundly impact properties of bulk metallic glasses. Here,
we systematically reduce the length scale of Au and Pt-based metallic glasses and study …

Geological timescales' aging effects of lunar glasses

Z Chen, Y Zhao, X Chi, Y Yan, J Shen, M Zou… - Science …, 2023 - science.org
Physical aging is a long-lasting research hot spot in the glass community, yet its long-term
effects remain unclear because of the limited experimental time. In this study, we discover …

Physical aging of selenium glass: Assessing the double mechanism of equilibration and the crystallization process

A Morvan, N Delpouve, A Vella… - Journal of Non-Crystalline …, 2021 - Elsevier
This work focuses on the study of the physical aging of a selenium glass by differential
scanning calorimetry (DSC) and fast scanning calorimetry (FSC). Aged samples of 30 and …

Physical aging of hydroxypropyl methylcellulose acetate succinate via enthalpy recovery

Y Seo, B Zuo, D Cangialosi, RD Priestley - Soft Matter, 2022 - pubs.rsc.org
Amorphous solid dispersions (ASDs) utilize the kinetic stability of the amorphous state to
stabilize drug molecules within a glassy polymer matrix. Therefore, understanding the glassy …

Kauzmann paradox: A possible crossover due to diminishing local excitations

XY Gao, CY Ong, CS Lee, CT Yip, HY Deng, CH Lam - Physical Review B, 2023 - APS
The configurational entropy of supercooled liquids extrapolates to zero at the Kauzmann
temperature, causing a crisis called the Kauzmann paradox. Here, using a class of …