[HTML][HTML] Coordination chemistry of elemental phosphorus
This review comprehensively covers the coordination chemistry of elemental phosphorus
during the years 2011–2020. The main part is dedicated to the activation of white …
during the years 2011–2020. The main part is dedicated to the activation of white …
The chemistry of yellow arsenic
M Seidl, G Balázs, M Scheer - Chemical reviews, 2019 - ACS Publications
The generation and handling of the light-sensitive and metastable yellow arsenic (As4) is
extremely challenging. In view of recent breakthroughs in synthesizing As4 storage …
extremely challenging. In view of recent breakthroughs in synthesizing As4 storage …
From an Fe 2 P 3 complex to FeP nanoparticles as efficient electrocatalysts for water-splitting
In large-scale, hydrogen production from water-splitting represents the most promising
solution for a clean, recyclable, and low-cost energy source. The realization of viable …
solution for a clean, recyclable, and low-cost energy source. The realization of viable …
Uranium (III)–phosphorus (III) synergistic activation of white phosphorus and arsenic
The study of small-molecule activation by f-block elements still lags far behind that of
transition metals. Although a few uranium complexes have been reported to activate …
transition metals. Although a few uranium complexes have been reported to activate …
Stabilization of intermediate spin states in mixed-valent diiron dichalcogenide complexes
JT Henthorn, GE Cutsail III, T Weyhermüller… - Nature Chemistry, 2022 - nature.com
The electronic structure and ground spin states, S, observed for mixed-valent iron–sulfur
dimers (FeII-FeIII) are typically determined by the Heisenberg exchange interaction, J, that …
dimers (FeII-FeIII) are typically determined by the Heisenberg exchange interaction, J, that …
Iron (I) and Iron (II) Amido-imidazolin-2-imine Complexes as Catalysts for H/D Exchange in Hydrosilanes
NU Din Reshi, D Bockfeld, D Baabe, L Denker… - ACS …, 2024 - ACS Publications
The unsymmetrical amino-imidazolin-2-imine ligand [HAmIm, 1, 2-(DippNH)–C6H4–N= C (N
i PrCMe) 2] is employed in the synthesis of the iron (I) arene complex [(AmIm) Fe (η 6 …
i PrCMe) 2] is employed in the synthesis of the iron (I) arene complex [(AmIm) Fe (η 6 …
Direct functionalization of white phosphorus with anionic dicarbenes and mesoionic carbenes: facile access to 1, 2, 3-triphosphol-2-ides
D Rottschäfer, S Blomeyer, B Neumann… - Chemical …, 2019 - pubs.rsc.org
A series of unique C2P3-ring compounds [(ADCAr) P3](ADCAr= ArC {(DippN) C} 2; Dipp= 2,
6-iPr2C6H3; Ar= Ph 4a, 3-MeC6H44b, 4-MeC6H44c, and 4-Me2NC6H44d) are readily …
6-iPr2C6H3; Ar= Ph 4a, 3-MeC6H44b, 4-MeC6H44c, and 4-Me2NC6H44d) are readily …
Transition metal complexes of the naked pnictide elements
KH Whitmire - Coordination Chemistry Reviews, 2018 - Elsevier
Even though transition metal compounds containing “naked” pnictide elements (E) have
been known for many decades now, the chemistry of this interesting class of compounds …
been known for many decades now, the chemistry of this interesting class of compounds …
Direct Functionalization of White Phosphorus to Cyclotetraphosphanes: Selective Formation of Four P–C Bonds
S Du, J Yang, J Hu, Z Chai, G Luo, Y Luo… - Journal of the …, 2019 - ACS Publications
Converting elemental white phosphorus directly into organophosphorus or polyphosphorus
is meaningful, challenging and attractive. The ate-complexes of aluminacyclopentadienes …
is meaningful, challenging and attractive. The ate-complexes of aluminacyclopentadienes …
Selective derivatization of a hexaphosphane from functionalization of white phosphorus
F Hennersdorf, J Frötschel… - Journal of the American …, 2017 - ACS Publications
The reaction of LGa (L= Dipp (4-(Dipp-imino) pent-2-en-2-yl) amide; Dipp: 2, 6-
diisopropylphenyl) and white phosphorus was revisited. A plethora of unprecedented …
diisopropylphenyl) and white phosphorus was revisited. A plethora of unprecedented …