Electrochemistry of corroles in nonaqueous media
This review describes the known electrochemistry of corroles in nonaqueous media from
1980 until the present. The outline of the review is grouped according to the periodic table …
1980 until the present. The outline of the review is grouped according to the periodic table …
Porphyrinoids as a platform of stable radicals
D Shimizu, A Osuka - Chemical Science, 2018 - pubs.rsc.org
The non-innocent ligand nature of porphyrins was observed for compound I in enzymatic
cycles of cytochrome P450. Such porphyrin radicals were first regarded as reactive …
cycles of cytochrome P450. Such porphyrin radicals were first regarded as reactive …
Well-defined organometallic Copper (III) complexes: Preparation, characterization and reactivity
H Liu, Q Shen - Coordination Chemistry Reviews, 2021 - Elsevier
Organocopper (III) species were generally considered as the key intermediates in a variety
of copper-catalyzed cross-coupling reactions, aerobic oxidations, as well as enzyme …
of copper-catalyzed cross-coupling reactions, aerobic oxidations, as well as enzyme …
A Bio‐inspired Cu4O4 Cubane: Effective Molecular Catalysts for Electrocatalytic Water Oxidation in Aqueous Solution
Inspired by the cubic Mn4CaO5 cluster of natural oxygen‐evolving complex in Photosystem
II, tetrametallic molecular water oxidation catalysts, especially M4O4 cubane‐like clusters …
II, tetrametallic molecular water oxidation catalysts, especially M4O4 cubane‐like clusters …
Spectroscopic Evidence for a 3d10 Ground State Electronic Configuration and Ligand Field Inversion in [Cu(CF3)4]1–
RC Walroth, JT Lukens, SN MacMillan… - Journal of the …, 2016 - ACS Publications
The contested electronic structure of [Cu (CF3) 4] 1–is investigated with UV/visible/near IR
spectroscopy, Cu K-edge X-ray absorption spectroscopy, and 1s2p resonant inelastic X-ray …
spectroscopy, Cu K-edge X-ray absorption spectroscopy, and 1s2p resonant inelastic X-ray …
Synergistic copper nanoparticles and adjacent single atoms on biomass-derived N-doped carbon toward overall water splitting
W Zhang, R Liu, Z Fan, H Wen, Y Chen, R Lin… - Inorganic Chemistry …, 2023 - pubs.rsc.org
The rational design of effective heterogeneous electrocatalysts with an appropriate
electronic structure and active sites is crucial for efficient overall water splitting. Atomic-level …
electronic structure and active sites is crucial for efficient overall water splitting. Atomic-level …
Electronic structure of copper corroles
The ground state electronic structure of copper corroles has been a topic of debate and
revision since the advent of corrole chemistry. Computational studies formulate neutral Cu …
revision since the advent of corrole chemistry. Computational studies formulate neutral Cu …
X-ray absorption spectroscopy as a probe of ligand noninnocence in metallocorroles: the case of copper corroles
The question of ligand noninnocence in Cu corroles has long been a topic of discussion.
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …
Presented herein is a Cu K-edge X-ray absorption spectroscopy (XAS) study, which …
Water oxidation catalysis by mono-and binuclear iron corroles
Considering the overwhelming importance and involvement of iron in numerous biocatalytic
processes, the scarceness of synthetic iron complexes as water oxidation catalysts (WOCs) …
processes, the scarceness of synthetic iron complexes as water oxidation catalysts (WOCs) …
Oxidation and reduction of redox-sensitive elements in the presence of humic substances in subsurface environments: A review
S Lee, Y Roh, DC Koh - Chemosphere, 2019 - Elsevier
The oxidation and reduction (redox) processes of redox-sensitive elements (RSE) in the
presence of humic substances (HS) have become a significantly important issue in the terms …
presence of humic substances (HS) have become a significantly important issue in the terms …