Photodriven Sm (III)-to-Sm (II) Reduction for Catalytic Applications

CM Johansen, EA Boyd, DE Tarnopol… - Journal of the American …, 2024 - ACS Publications
The selectivity of SmI2 as a one electron-reductant motivates the development of methods
for reductive Sm-catalysis. Photochemical methods for SmI2 regeneration are desired for …

Regio‐and Diastereoselective Synthesis of Polysubstituted Piperidines Enabled by Boronyl Radical‐Catalyzed (4+ 2) Cycloaddition

Z Ding, Z Wang, Y Wang, X Wang, Y Xue… - Angewandte …, 2024 - Wiley Online Library
Piperidines are widely present in small molecule drugs and natural products. Despite many
methods have been developed for their synthesis, new approaches to polysubstituted …

Broad-Scope (3+ 2) Cycloaddition of Cyclopropanes and Alkynes Enabled by Boronyl Radical Catalysis

J Wen, Z Ding, P Li - Organic Letters, 2024 - ACS Publications
Cyclopentene skeletons are ubiquitous in natural products and small molecule drugs. The
(3+ 2) cycloaddition of cyclopropanes and alkynes represents an efficient and atom …

Computational Study of SmI2-Catalyzed Intermolecular Couplings of Cyclopropyl Ketones: Links between the Structure and Reactivity

S Yu, C Romano, DJ Procter… - The Journal of organic …, 2024 - ACS Publications
SmI2-catalyzed intermolecular coupling reactions of cyclopropyl ketones with alkenes or
alkynes offer an efficient strategy for furnishing diverse five-membered ring-containing …

Pyridine‐Boryl Radical‐Catalyzed [3+ 2] Cycloadditions of Alkyne‐Tethered Cyclopropyl Ketones

H Huang, XD An, YF Wang, YX Tan… - Advanced Synthesis & … - Wiley Online Library
Bicyclo [3.3. 0] octanes represent crucial structural motifs found in various bioactive natural
compounds. In this study, we present the first metal‐free formal [3+ 2] cycloadditions of …